Thermodynamic and Kinetic Study of Cleavage of the N–O Bond of N-Oxides by a Vanadium(III) Complex: Enhanced Oxygen Atom Transfer Reaction Rates for Adducts of Nitrous Oxide and Mesityl Nitrile Oxide

Taryn D. Palluccio; Elena V. Rybak-Akimova; Subhojit Majumdar; Xiaochen Cai; Megan Chui; Manuel Temprado; Jared S. Silvia; Anthony F. Cozzolino; Daniel Tofan; Alexandra Velian; Christopher C. Cummins; Burjor Captain; Carl D. Hoff

doi:10.1021/ja405395z

Thermodynamic and Kinetic Study of Cleavage of the N–O Bond of N-Oxides by a Vanadium(III) Complex: Enhanced Oxygen Atom Transfer Reaction Rates for Adducts of Nitrous Oxide and Mesityl Nitrile Oxide

Journal of the American Chemical Society ◽

10.1021/ja405395z ◽

2013 ◽

Vol 135 (30) ◽

pp. 11357-11372 ◽

Cited By ~ 28

Author(s):

Taryn D. Palluccio ◽

Elena V. Rybak-Akimova ◽

Subhojit Majumdar ◽

Xiaochen Cai ◽

Megan Chui ◽

...

Keyword(s):

Nitrous Oxide ◽

Oxygen Atom ◽

Kinetic Study ◽

Transfer Reaction ◽

Reaction Rates ◽

Nitrile Oxide ◽

Atom Transfer ◽

Oxygen Atom Transfer

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Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

Inorganic Chemistry Frontiers ◽

10.1039/d1qi00308a ◽

2021 ◽

Author(s):

Leila G. Ranis ◽

Jacqueline Gianino ◽

Justin M. Hoffman ◽

Seth N. Brown

Keyword(s):

Oxygen Atom ◽

Transfer Reaction ◽

Transfer Reactions ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Oxygen Atom Transfer Reactions ◽

Atom Transfer Reactions ◽

Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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The important role of an unpaired d-electron for terminal oxygen atom transfer reaction of the (hydroperoxo) iron(III) compound

Polyhedron ◽

10.1016/s0277-5387(02)01362-1 ◽

2003 ◽

Vol 22 (2) ◽

pp. 293-297 ◽

Cited By ~ 2

Author(s):

Yuzo Nishida ◽

Sayo Ito ◽

Satoshi Nishino

Keyword(s):

Oxygen Atom ◽

Transfer Reaction ◽

Terminal Oxygen Atom ◽

Atom Transfer ◽

Oxygen Atom Transfer

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Photochemical oxygen-atom transfer reaction by heterocycle N-oxides involving a single-electron transfer process: oxidative demethylation of N,N-dimethylaniline

Journal of the American Chemical Society ◽

10.1021/ja00279a063 ◽

1986 ◽

Vol 108 (19) ◽

pp. 6039-6041 ◽

Cited By ~ 27

Author(s):

Magoichi. Sako ◽

Kaoru. Shimada ◽

Kosaku. Hirota ◽

Yoshifumi. Maki

Keyword(s):

Electron Transfer ◽

Oxygen Atom ◽

Transfer Process ◽

Transfer Reaction ◽

Single Electron ◽

Atom Transfer ◽

Single Electron Transfer ◽

Oxygen Atom Transfer ◽

Electron Transfer Process ◽

Oxidative Demethylation

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Oxygen-atom transfer from nitrous oxide. Synthesis and structure of a zirconocene oxametallacyclobutene complex

Journal of the American Chemical Society ◽

10.1021/ja00229a047 ◽

1988 ◽

Vol 110 (21) ◽

pp. 7215-7217 ◽

Cited By ~ 27

Author(s):

G. Alan. Vaughan ◽

Gregory L. Hillhouse ◽

Robert T. Lum ◽

Stephen L. Buchwald ◽

Arnold L. Rheingold

Keyword(s):

Nitrous Oxide ◽

Oxygen Atom ◽

Atom Transfer ◽

Oxygen Atom Transfer

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Oxygen-Atom Transfer from Nitrous Oxide to an Organonickel(II) Phosphine Complex. Syntheses and Reactions of New Nickel(II) Aryloxides and the Crystal Structure of [cyclic] (Me2PCH2CH2PMe2)Ni(O-o-C6H4CMe2CH2)

Organometallics ◽

10.1021/om00001a062 ◽

1995 ◽

Vol 14 (1) ◽

pp. 456-460 ◽

Cited By ~ 55

Author(s):

Kwangmo Koo ◽

Gregory L. Hillhouse ◽

Arnold L. Rheingold

Keyword(s):

Crystal Structure ◽

Nitrous Oxide ◽

Oxygen Atom ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Phosphine Complex

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Gas-phase reactions of transition metal carbonyl anions and atomic metal anions with nitrous oxide and dioxygen: Oxygen atom transfer and ligand exchange in reactions with nitrous oxide

Rapid Communications in Mass Spectrometry ◽

10.1002/rcm.1290081108 ◽

1994 ◽

Vol 8 (11) ◽

pp. 895-905 ◽

Cited By ~ 5

Author(s):

Klaas Jan van den Berg ◽

Steen Ingemann ◽

Nico M. M. Nibbering ◽

Ian K. Gregor

Keyword(s):

Nitrous Oxide ◽

Transition Metal ◽

Oxygen Atom ◽

Gas Phase ◽

Ligand Exchange ◽

Metal Carbonyl ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Gas Phase Reactions ◽

Metal Anions

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A novel oxygen atom transfer reaction. Isomerization of nickel(II) octaethylporphyrin N-oxide to nickel(II) octaethyloxochlorin

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)84399-6 ◽

1986 ◽

Vol 115 (2) ◽

pp. L45-L46 ◽

Cited By ~ 4

Author(s):

Alan L. Balch ◽

Y.W. Chan

Keyword(s):

Oxygen Atom ◽

Transfer Reaction ◽

Atom Transfer ◽

Oxygen Atom Transfer

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OXYGEN ATOM TRANSFER REACTION THE REACTION OF CARBONYL COMPOUNDS WITH DIOXYGEN COMPLEXES

Chemistry Letters ◽

10.1246/cl.1981.1639 ◽

1981 ◽

Vol 10 (11) ◽

pp. 1639-1642 ◽

Cited By ~ 5

Author(s):

Shun’ichi Aida ◽

Hiroyuki Ohta ◽

Yoshio Kamiya

Keyword(s):

Oxygen Atom ◽

Carbonyl Compounds ◽

Transfer Reaction ◽

Atom Transfer ◽

Oxygen Atom Transfer

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Tuning Iridium(I) PCcarbeneP Frameworks for Facile Cooperative N2O Reduction

10.26434/chemrxiv.6771695 ◽

2018 ◽

Author(s):

Joel D. Smith ◽

Edwina Chih ◽

Warren Piers ◽

Denis M. Spasyuk

Keyword(s):

Double Bond ◽

Oxygen Atom ◽

Kinetic Study ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

N2o Reduction ◽

Pincer Ligand ◽

Selective Reaction ◽

Carbon Double Bond

A semiquantitative kinetic study correlates the rate of oxygen atom transfer from N2O to an iridium carbon double bond with the donor properties of six PCcarbeneP pincer ligand frameworks. Two new rigid, electron rich ligands are described and shown to be the most effective for rapid, selective reaction with N2O.

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