Giant Ising-Type Magnetic Anisotropy in Trigonal Bipyramidal Ni(II) Complexes: Experiment and Theory

2013 ◽  
Vol 135 (8) ◽  
pp. 3017-3026 ◽  
Author(s):  
Renaud Ruamps ◽  
Rémi Maurice ◽  
Luke Batchelor ◽  
Martial Boggio-Pasqua ◽  
Régis Guillot ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Trigonal Bipyramidal

scholarly journals Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

2018 ◽  
Vol 47 (28) ◽  
pp. 9237-9240 ◽  
Author(s):  
Alexandra Collet ◽  
Gavin A. Craig ◽  
María José Heras Ojea ◽  
Lakshmi Bhaskaran ◽  
Claire Wilson ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Magnetic Relaxation ◽  
Easy Plane ◽  
Trigonal Bipyramidal ◽  
Slow Magnetic Relaxation

Incorporation of a trigonal bipyramidal CoII centre in {CoIICoIII2} leads to a large, easy-plane magnetic anisotropy and slow magnetic relaxation.

scholarly journals In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(ii)

2019 ◽  
Vol 10 (25) ◽  
pp. 6354-6361 ◽  
Author(s):  
Moya A. Hay ◽  
Arup Sarkar ◽  
Gavin A. Craig ◽  
Lakshmi Bhaskaran ◽  
Joscha Nehrkorn ◽  
...  
Keyword(s):  
Magnetic Resonance ◽  
Magnetic Anisotropy ◽  
Ab Initio ◽  
Frequency Domain ◽  
Easy Plane ◽  
Ab Initio Methods ◽  
Trigonal Bipyramidal

Symmetry control using DABCO generates a large easy-plane magnetic anisotropy with zero rhombic anisotropy.

Symmetry-Based Magnetic Anisotropy in the Trigonal Bipyramidal Cluster [Tp2(Me3tacn)3Cu3Fe2(CN)6]4+

2006 ◽  
Vol 128 (22) ◽  
pp. 7162-7163 ◽  
Author(s):  
Cai-Feng Wang ◽  
Jing-Lin Zuo ◽  
Bart M. Bartlett ◽  
You Song ◽  
Jeffrey R. Long ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Trigonal Bipyramidal

scholarly journals A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

2020 ◽  
Vol 56 (50) ◽  
pp. 6826-6829
Author(s):  
Moya A. Hay ◽  
Arup Sarkar ◽  
Gavin A. Craig ◽  
Katie E. R. Marriott ◽  
Claire Wilson ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Coordination Sphere ◽  
Magnetic Relaxation ◽  
Geometric Distortion ◽  
Trigonal Bipyramidal ◽  
Slow Magnetic Relaxation

Minimising geometric distortion in the first coordination sphere generates a large axial magnetic anisotropy in trigonal bipyramidal Fe(ii) and rare slow magnetic relaxation.

scholarly journals Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure

2018 ◽  
Vol 9 (6) ◽  
pp. 1551-1559 ◽  
Author(s):  
Gavin A. Craig ◽  
Arup Sarkar ◽  
Christopher H. Woodall ◽  
Moya A. Hay ◽  
Katie E. R. Marriott ◽  
...  
Keyword(s):  
High Pressure ◽  
Magnetic Anisotropy ◽  
Ab Initio ◽  
Trigonal Bipyramidal ◽  
Synergistic Combination

The synergistic combination of high pressure techniques with ab initio methods creates a powerful tool to understand giant magnetic anisotropy.

scholarly journals Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(ii)

2015 ◽  
Vol 6 (12) ◽  
pp. 6823-6828 ◽  
Author(s):  
Katie E. R. Marriott ◽  
Lakshmi Bhaskaran ◽  
Claire Wilson ◽  
Marisa Medarde ◽  
Stefan T. Ochsenbein ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
High Spin ◽  
Magnetic Relaxation ◽  
High Field ◽  
Magnetic Studies ◽  
Trigonal Bipyramidal ◽  
Slow Magnetic Relaxation

High-field EPR and magnetic studies of a high-spin Ni(ii) trigonal bipyramidal complex reveal a giant axial magnetic anisotropy and a rare field-induced slow magnetic relaxation.

Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co(ii) complexes

2014 ◽  
Vol 5 (9) ◽  
pp. 3418 ◽  
Author(s):  
Renaud Ruamps ◽  
Luke J. Batchelor ◽  
Régis Guillot ◽  
Georges Zakhia ◽  
Anne-Laure Barra ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Trigonal Bipyramidal

scholarly journals Investigation of the magnetic anisotropy in a series of trigonal bipyramidal Mn(ii) complexes

2019 ◽  
Vol 48 (41) ◽  
pp. 15480-15486
Author(s):  
Moya A. Hay ◽  
Arup Sarkar ◽  
Katie E. R. Marriott ◽  
Claire Wilson ◽  
Gopalan Rajaraman ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Trigonal Symmetry ◽  
Trigonal Bipyramidal

The trigonal symmetry around the MnII ion is fine-tuned to control the rhombic zero-field splitting.

Sign in / Sign up

Export Citation Format

Share Document