Main-Chain Optically Active Riboflavin Polymer for Asymmetric Catalysis and Its Vapochromic Behavior

Hiroki Iida; Soichiro Iwahana; Tomohisa Mizoguchi; Eiji Yashima

doi:10.1021/ja306159t

Main-Chain Optically Active Riboflavin Polymer for Asymmetric Catalysis and Its Vapochromic Behavior

Journal of the American Chemical Society ◽

10.1021/ja306159t ◽

2012 ◽

Vol 134 (36) ◽

pp. 15103-15113 ◽

Cited By ~ 69

Author(s):

Hiroki Iida ◽

Soichiro Iwahana ◽

Tomohisa Mizoguchi ◽

Eiji Yashima

Keyword(s):

Asymmetric Catalysis ◽

Main Chain ◽

Optically Active ◽

Vapochromic Behavior

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Correction to Main-Chain Optically Active Riboflavin Polymer for Asymmetric Catalysis and Its Vapochromic Behavior

Journal of the American Chemical Society ◽

10.1021/ja310013j ◽

2012 ◽

Vol 134 (43) ◽

pp. 18150-18150 ◽

Cited By ~ 4

Author(s):

Hiroki Iida ◽

Soichiro Iwahana ◽

Tomohisa Mizoguchi ◽

Eiji Yashima

Keyword(s):

Asymmetric Catalysis ◽

Main Chain ◽

Optically Active ◽

Vapochromic Behavior

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Main-Chain Ionic Chiral Polymers: Synthesis of Optically Active Quaternary Ammonium Sulfonate Polymers and Their Application in Asymmetric Catalysis

Journal of the American Chemical Society ◽

10.1021/ja909972d ◽

2010 ◽

Vol 132 (9) ◽

pp. 2864-2865 ◽

Cited By ~ 54

Author(s):

Shinichi Itsuno ◽

Devproshad K. Paul ◽

M. A. Salam ◽

Naoki Haraguchi

Keyword(s):

Asymmetric Catalysis ◽

Quaternary Ammonium ◽

Main Chain ◽

Optically Active ◽

Chiral Polymers

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Synthesis and characterization of new optically active poly(amide-imide)s containing 1,3,4-oxadiazole moiety in the main chain

Polymer Bulletin ◽

10.1007/s00289-009-0203-3 ◽

2009 ◽

Vol 65 (4) ◽

pp. 319-332 ◽

Cited By ~ 9

Author(s):

Khalil Faghihi ◽

Hassan Moghanian

Keyword(s):

Main Chain ◽

Optically Active ◽

Synthesis And Characterization

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Conjugated Polymers with Main Chain Chirality. 3. Synthesis of Optically Active Poly(aryleneethynylene)s

Macromolecules ◽

10.1021/ma960250t ◽

1996 ◽

Vol 29 (15) ◽

pp. 5083-5090 ◽

Cited By ~ 25

Author(s):

Liang Ma ◽

Qiao-Sheng Hu ◽

Kwon Yon Musick ◽

Dilrukshi Vitharana ◽

Chi Wu ◽

...

Keyword(s):

Conjugated Polymers ◽

Main Chain ◽

Optically Active

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Chiral Polymers-The Synthesis of Optically Active Vinyl and Vinylidene Polymers with Main Chain Chirality

Materials Science and Technology ◽

10.1002/9783527603978.mst0233 ◽

2013 ◽

Author(s):

Günter Wulff

Keyword(s):

Main Chain ◽

Optically Active ◽

Chiral Polymers

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ChemInform Abstract: Synthesis of Optically Active 2-Siloxycyclopropanecarboxylates by Asymmetric Catalysis. Part 4. Influence of Nucleophilicity of Silyl Enol Ethers on Stereoselectivities in Asymmetric Cyclopropanation Reactions.

ChemInform ◽

10.1002/chin.199729035 ◽

2010 ◽

Vol 28 (29) ◽

pp. no-no

Author(s):

R. SCHUMACHER ◽

H.-U. REISSIG

Keyword(s):

Asymmetric Catalysis ◽

Optically Active ◽

Enol Ethers ◽

Silyl Enol Ethers ◽

Asymmetric Cyclopropanation

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Methacrylic polymers bearing side-chain permanent dipole azobenzene chromophores spaced from the main chain by chiral moieties, 3 a Synthesis and chiroptical properties of the homopolymer of (R)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)- pyrrolidine and of copolymers with the enantiomeric monomer (S)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)- pyrrolidine

e-Polymers ◽

10.1515/epoly.2003.3.1.480 ◽

2003 ◽

Vol 3 (1) ◽

Author(s):

Luigi Angiolini ◽

Loris Giorgini ◽

Elisabetta Salatelli

Keyword(s):

Radical Polymerization ◽

Optical Activity ◽

Main Chain ◽

Optically Active ◽

Side Chain ◽

Chiroptical Properties

Abstract The optically active photochromic homopolymer deriving from radical polymerization of the monomer (R)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)- pyrrolidine, containing a chiral group of one prevailing configuration interposed between the methacrylic moiety and the photochromic azoaromatic chromophore, has been synthesized and characterized. Copolymers with the enantiomeric monomer (S)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)pyrrolidine have also been prepared in order to evaluate the effect on the overall optical activity of side chain chiral groups of opposite configuration in various ratios. The spectroscopic and chiroptical properties in solution of the polymeric derivatives have been assessed.

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