Poly(ionic liquid) Complex with Spontaneous Micro-/Mesoporosity: Template-Free Synthesis and Application as Catalyst Support

2012 ◽  
Vol 134 (29) ◽  
pp. 11852-11855 ◽  
Author(s):  
Qiang Zhao ◽  
Pengfei Zhang ◽  
Markus Antonietti ◽  
Jiayin Yuan
Keyword(s):  
Ionic Liquid ◽  
Catalyst Support ◽  
Template Free ◽  
Poly Ionic Liquid

Template-free fabrication of magnetic mesoporous poly(ionic liquid)s: efficient interfacial catalysts for hydrogenation reaction and transesterification of soybean oil

2022 ◽  
Author(s):  
Sheng-Nan Li ◽  
Xiaotong Lu ◽  
Qi Liu ◽  
Limin Wang ◽  
Yu-Jing Liu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Soybean Oil ◽  
Hydrogenation Reaction ◽  
Sustainable Production ◽  
Human Society ◽  
Double Response ◽  
Template Free ◽  
Poly Ionic Liquid

Green sustainable production is very important for the development of human society and environment. In this study, Pickering interfacial catalysts (Pd-p(xTEMPA-yFDABCO-zDVB)@Fe3O4) with CO2 and magnetic double response were prepared by...

A Novel Poly(Ionic Liquid) as the Thermal Insulating Material

2020 ◽  
Vol 13 (3) ◽  
pp. 241-247
Author(s):  
Wenxin Wei ◽  
Guifeng Ma ◽  
Hongtao Wang ◽  
Jun Li
Keyword(s):  
Thermal Conductivity ◽  
Ionic Liquid ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Flame Resistance ◽  
Insulating Material ◽  
Low Thermal Conductivity ◽  
Thermal Insulating ◽  
Poly Ionic Liquid

Objective: A new poly(ionic liquid)(PIL), poly(p-vinylbenzyltriphenylphosphine hexafluorophosphate) (P[VBTPP][PF6]), was synthesized by quaternization, anion exchange reaction, and free radical polymerization. Then a series of the PIL were synthesized at different conditions. Methods: The specific heat capacity, glass-transition temperature and melting temperature of the synthesized PILs were measured by differential scanning calorimeter. The thermal conductivities of the PILs were measured by the laser flash analysis method. Results: Results showed that, under optimized synthesis conditions, P[VBTPP][PF6] as the thermal insulator had a high glass-transition temperature of 210.1°C, high melting point of 421.6°C, and a low thermal conductivity of 0.0920 W m-1 K-1 at 40.0°C (it was 0.105 W m-1 K-1 even at 180.0°C). The foamed sample exhibited much low thermal conductivity λ=0.0340 W m-1 K-1 at room temperature, which was comparable to a commercial polyurethane thermal insulating material although the latter had a much lower density. Conclusion: In addition, mixing the P[VBTPP][PF6] sample into polypropylene could obviously increase the Oxygen Index, revealing its efficient flame resistance. Therefore, P[VBTPP][PF6] is a potential thermal insulating material.

Modular Platform for Synthesis of Poly(Ionic Liquid) Electrolytes for Electrochemical Applications in Supercapacitors

2021 ◽  
Vol 6 (15) ◽  
pp. 3795-3801
Author(s):  
Radostina Kalinova ◽  
Ivaylo Dimitrov ◽  
Christo Novakov ◽  
Svetlana Veleva ◽  
Antonia Stoyanova
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolytes ◽  
Electrochemical Applications ◽  
Modular Platform ◽  
Poly Ionic Liquid

Facile fabrication of self-reporting micellar and vesicular structures based on etching-ion exchange strategy of photonic composite spheres of poly(ionic liquid)

Nanoscale ◽  
2021 ◽  
Author(s):  
Ning Gao ◽  
Kang Zhou ◽  
Kai Feng ◽  
Wanlin Zhang ◽  
Jiecheng Cui ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ion Exchange ◽  
Chemical Environment ◽  
Facile Fabrication ◽  
Poly Ionic Liquid

Micellar and vesicular structures capable of sensing and reporting the chemical environment as well as facilely introducing user-defined functions make a vital contribution to constructing versatile compartmentalized systems. Herein, combing...

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