Uniform, Dense Arrays of Vertically Aligned, Large-Diameter Single-Walled Carbon Nanotubes

2012 ◽  
Vol 134 (13) ◽  
pp. 6018-6024 ◽  
Author(s):  
Zhao Jun Han ◽  
Kostya (Ken) Ostrikov
2009 ◽  
Vol 113 (10) ◽  
pp. 4125-4133 ◽  
Author(s):  
Cary L. Pint ◽  
Sean T. Pheasant ◽  
A. Nicholas G. Parra-Vasquez ◽  
Charles Horton ◽  
Yaqiong Xu ◽  
...  

2013 ◽  
Vol 52 (49) ◽  
pp. 13080-13085 ◽  
Author(s):  
Jean-Hubert Olivier ◽  
Pravas Deria ◽  
Jaehong Park ◽  
Amar Kumbhar ◽  
Maria Andrian-Albescu ◽  
...  

2021 ◽  
Vol 69 ◽  
pp. 11-21
Author(s):  
Ping Zhang ◽  
Wen Hui Yi ◽  
Bai Lei ◽  
Jin Feng Zhou ◽  
Yi Long Tian ◽  
...  

Due to the difficulty in the selective synthesis of semiconductor (s-) and metal (m-) single-walled carbon nanotubes (SWCNTs), we still need to explore the selective extraction technology of s-SWCNTs. Using Poly[9-(1-octylonoyl)-9H-carbazole-2,7-diyl] (PCz) extraction of s-SWCNTs has attracted extensive attention in recent years, because it can selective extraction of large-diameter s-SWCNTs with high purity. However, influence of the molecular weight of this polymer on the s-SWCNTs selective extraction properties remains unclear. In this study, we used PCz with different average molecular weights to study the ability of selective extraction s-SWCNTs from pristine arc discharge carbon nanotubes. Spectra studies indicate that compared to the PCz with lower molecular weight, the PCz with higher molecular weight has better selective extraction ability, and can help to obtain s-SWCNTs with higher purity (>99%) and high yield. FETs devices have been prepared by s-SWCNTs obtained via PCz with higher molecular weight exhibit higher on/off ratio, lower off current and lower subthreshold swing. This work offers a reference of the design and synthesis of PCz polymer that performs sufficient selective ability in extracting s-SWCNTs with promising applications.


Author(s):  
Kei Ishikawa ◽  
Hai Duong ◽  
Junichiro Shiomi ◽  
Shigeo Maruyama

Evaporation of different metals (Au, Ti, Al and Pd) onto Vertically-Aligned Single-Walled Carbon Nanotubes (VASWNT) has been studied. Observations through Scanning Electron Microscopy (SEM) showed a clear metal-dependence of the deposition layer structure on top of the VASWNT, reflecting the variation of wettability and cohesive energy of each metal. These characteristics also influence the structures of the metal penetrated through the top surface into VASWNT film, where metal forms particles inside VASWNT film except for Ti. A simple annealing technique to remove metals penetrated in the SWNT films is demonstrated. Some peculiar morphologies found during the processes are also presented.


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