Ordered Mesoporous Platinum@Graphitic Carbon Embedded Nanophase as a Highly Active, Stable, and Methanol-Tolerant Oxygen Reduction Electrocatalyst

2012 ◽  
Vol 134 (4) ◽  
pp. 2236-2245 ◽  
Author(s):  
Zhangxiong Wu ◽  
Yingying Lv ◽  
Yongyao Xia ◽  
Paul A. Webley ◽  
Dongyuan Zhao
Keyword(s):  
Oxygen Reduction ◽  
Graphitic Carbon ◽  
Highly Active ◽  
Ordered Mesoporous ◽  
Methanol Tolerant ◽  
Mesoporous Platinum

Nanoporous PdCu alloys as highly active and methanol-tolerant oxygen reduction electrocatalysts

2013 ◽  
Vol 38 (24) ◽  
pp. 10029-10038 ◽  
Author(s):  
Huan Zhang ◽  
Qin Hao ◽  
Haoran Geng ◽  
Caixia Xu
Keyword(s):  
Oxygen Reduction ◽  
Highly Active ◽  
Methanol Tolerant

A highly active and durable iron/cobalt alloy catalyst encapsulated in N-doped graphitic carbon nanotubes for oxygen reduction reaction by a nanofibrous dicyandiamide template

2018 ◽  
Vol 6 (14) ◽  
pp. 5962-5970 ◽  
Author(s):  
Li An ◽  
Ning Jiang ◽  
Biao Li ◽  
Shixin Hua ◽  
Yutong Fu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Graphitic Carbon ◽  
Cobalt Alloy ◽  
Iron Cobalt ◽  
Highly Active ◽  
Alloy Catalyst

The FeCo@N-GCNT-FD catalyst exhibits enhanced intrinsic activities and excellent durability for the oxygen reduction reaction.

Facile Synthesis of Polyhedral Pd Nanocrystals as a Highly Active and Methanol-Tolerant Electrocatalyst for Oxygen Reduction

2017 ◽  
Vol 2 (29) ◽  
pp. 9291-9297 ◽  
Author(s):  
Yikui Zeng ◽  
SiSi Tian ◽  
Dongsheng Wang ◽  
Hailin Dong ◽  
Xiaoyang Cheng ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Facile Synthesis ◽  
Highly Active ◽  
Methanol Tolerant

scholarly journals Highly Active and Durable Transition Metal-Coordinated Nitrogen Doped Carbon Electrocatalyst for Oxygen Reduction Reaction in Neutral Media

2020 ◽  
Vol 141 ◽  
pp. 01005
Author(s):  
Kriangsak Ketpang ◽  
Apikom Boonkitkoson ◽  
Nattawan Pitipuech ◽  
Chedthawut Poompipatpong ◽  
Jakkid Sanetuntikul ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Precious Metal ◽  
Low Cost ◽  
Reduction Reaction ◽  
Graphitic Carbon ◽  
Metal Catalyst ◽  
Highly Active ◽  
Neutral Media ◽  
Nitrogen Doped Carbon

The major technical obstacles in commercialization of microbial fuel cell technology are the sluggish kinetic, high cost, and poor durability of an air cathode electrocatalyst. This research aimed to synthesize the highly active, stable and low cost non-precious metal catalyst to replace the expensive Pt electrocatalyst using a simple, low cost and scalable method. The Fe3C and Fe-N-C catalysts were prepared by direct heating the precursors under autogenic pressure conditions. X-ray diffraction pattern revealed the phase of Fe3C sample was cohenite Fe3C and graphitic carbon, while the phase of Fe-N-C catalyst was only graphitic carbon. The morphology of the synthesized catalysts was a highly porous structure with nanoparticle morphology. The surface area of the Fe3C and the Fe-N-C catalysts was 295 and 377 m2 g-1, respectively. The oxygen reduction reaction (ORR) activity of Fe-N-C catalyst was more active than Fe3C catalyst. The ORR performance of Fe-N-C catalyst exhibited about 1.6 times more superior to that of the noble Pt/C catalyst. In addition, the Fe-N-C catalyst was durable to operate under neutral media. Thus, a novel autogenic pressure technique was a promising method to effectively prepare an highly active and durable non-precious metal catalyst to replace the precious Pt/C catalyst.

Sign in / Sign up

Export Citation Format

Share Document