Light-Emitting Conjugated Polymers with Microporous Network Architecture: Interweaving Scaffold Promotes Electronic Conjugation, Facilitates Exciton Migration, and Improves Luminescence

2011 ◽  
Vol 133 (44) ◽  
pp. 17622-17625 ◽  
Author(s):  
Yanhong Xu ◽  
Long Chen ◽  
Zhaoqi Guo ◽  
Atsushi Nagai ◽  
Donglin Jiang
Keyword(s):  
Conjugated Polymers ◽  
Network Architecture ◽  
Light Emitting ◽  
Exciton Migration

Electronic structure studies of conducting polymers by electron energy-loss spectroscopy

1996 ◽  
Vol 54 ◽  
pp. 160-161
Author(s):  
J. Fink
Keyword(s):  
Electronic Structure ◽  
Conducting Polymers ◽  
Conjugated Polymers ◽  
Electron Acceptors ◽  
Electron Donors ◽  
Light Emitting ◽  
One Dimensional ◽  
New Class ◽  
Electrical Conductivities ◽  
Electron Energy Loss

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.

Color Variable Bipolar/AC Light-Emitting Devices Based on Conjugated Polymers

1997 ◽  
Author(s):  
Y. Z. Wang ◽  
D. D. Gebler ◽  
D. K. Fu ◽  
T. M. Swager ◽  
A. J. Epstein
Keyword(s):  
Conjugated Polymers ◽  
Light Emitting ◽  
Light Emitting Devices

scholarly journals Synthesis of π-Conjugated Polymers Containing Benzotriazole Units via Palladium-Catalyzed Direct C-H Cross-Coupling Polycondensation for OLEDs Applications

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 254
Author(s):  
Dong Han ◽  
Jingwen Li ◽  
Qiang Zhang ◽  
Zewang He ◽  
Zhiwei Wu ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Quantum Efficiency ◽  
Cross Coupling ◽  
Building Blocks ◽  
Gravimetric Analysis ◽  
19F Nmr Spectra ◽  
Light Emitting ◽  
Molecular Weights ◽  
Palladium Catalyzed ◽  
Red Luminescence

Four D-π-A conjugated polymers, namely P1–P4, which contain benzotriazole building blocks in their backbone as acceptor, are synthesized via palladium-catalyzed direct C-H cross-coupling polycondensation of 5,6-difluorobenzotriazole with different thiophene derivatives, including 3-octylthiophene, 2,2’-bithiophene, thieno[3,4-b][1,4]dioxine, and 4,4-dioctyl-4H-silolo-[3,2-b:4,5-b’]dithiophene as donor units, respectively. Taking the polymer P1 as an example, the chemical structure of the polymer is demonstrated by 1H and 19F NMR spectra. The optical, electrochemical, and thermal properties of these polymers are assessed by UV–vis absorption and fluorescence spectroscopy, cyclic voltammetry (CV), and thermal gravimetric analysis (TGA), respectively. DFT simulations of all polymers are also performed to understand their physicochemical properties. Furthermore, P1 and P2, which have relatively higher molecular weights and better fluorescent quantum efficiency than those of P3 and P4, are utilized as lighting emitters for organic light-emitting diodes (OLEDs), affording promising green and red luminescence with 0.07% and 0.14% of maximum external quantum efficiency, respectively, based on a device with an architecture of ITO/PEDOT:PSS/PTAA/the polymer emitting layer/TPBi/LiF/Al.

Conjugated Polymer Surfaces and Interfaces for Light-Emitting Devices

MRS Bulletin ◽  
1997 ◽  
Vol 22 (6) ◽  
pp. 46-51 ◽  
Author(s):  
W.R. Salaneck ◽  
J.L. Brédas
Keyword(s):  
Conjugated Polymers ◽  
Photoelectron Spectroscopy ◽  
Electronic Materials ◽  
Structural Information ◽  
Molecular Solids ◽  
Chemical Modeling ◽  
Polymer Leds ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Surfaces And Interfaces

Since the discovery of high electrical conductivity in doped polyacetylene in 1977, π-conjugated polymers have emerged as viable semiconducting electronic materials for numerous applications. In the context of polymer electronic devices, one must understand the nature of the polymer surface's electronic structure and the interface with metals. For conjugated polymers, photoelectron spectroscopy—especially in connection with quantum-chemical modeling—provides a maximum amount of both chemical and electronic structural information in one (type of) measurement. Some details of the early stages of interface formation with metals on the surfaces of conjugated polymers and model molecular solids in connection with polymer-based light-emitting devices (LEDs) are outlined. Then a chosen set of issues is summarized in a band structure diagram for a polymer LED, based upon a “clean calcium electrode” on the clean surface of a thin film of poly(p-phenylene vinylene) (PPV). This diagram helps to point out the complexity of the systems involved in polymer LEDs. No such thing as “an ideal metal-on-polymer contact” exists. There is always some chemistry occurring at the interface.

Band gap tuning of new light emitting conjugated polymers

2003 ◽  
Vol 21 (1-3) ◽  
pp. 199-203 ◽  
Author(s):  
Do-Hoon Hwang ◽  
Nam Sung Cho ◽  
Byung-Jun Jung ◽  
Hong-Ku Shim ◽  
Jeong-Ik Lee ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Band Gap ◽  
Light Emitting ◽  
Band Gap Tuning

Direct Sub-Micrometer-Patterning of Conjugated Polymers and Polymer Light-Emitting Devices by Electron Beam Lithography

2010 ◽  
Vol 211 (13) ◽  
pp. 1402-1407 ◽  
Author(s):  
Evelin Fisslthaler ◽  
Meltem Sezen ◽  
Harald Plank ◽  
Alexander Blümel ◽  
Stefan Sax ◽  
...  
Keyword(s):  
Electron Beam ◽  
Conjugated Polymers ◽  
Electron Beam Lithography ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Polymer Light Emitting Devices

Light-Emitting Diodes from Fluorene-Based π-Conjugated Polymers

2000 ◽  
Vol 12 (7) ◽  
pp. 1931-1936 ◽  
Author(s):  
Anne Donat-Bouillud ◽  
Isabelle Lévesque ◽  
Ye Tao ◽  
Marie D'Iorio ◽  
Serge Beaupré, ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Light Emitting Diodes ◽  
Light Emitting

Light-Emitting Diodes Based on Conjugated Polymers: Control of Colour and Efficiency

1992 ◽  
Vol 247 ◽  
Author(s):  
Paul L. Burn ◽  
A. B. Holmes ◽  
A. Kraft ◽  
A. R. Brown ◽  
D. D. C. Bradley ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Conjugated Polymers ◽  
Light Emitting Diodes ◽  
Fold Increase ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Metal Contacts ◽  
Light Emitting ◽  
Lithographic Patterning ◽  
Energy Gaps

ABSTRACTStudies of the effect of different electrode combinations on the device characteristics of simple three layer light-emitting diodes (LEDs) prepared with poly(ρ-phenylenevinylene) (PPV) as the emissive layer sandwiched between two metal contacts have shown that it is generally more difficult to inject electrons than holes. In order to improve the efficiency of such devices it is, therefore, necessary to develop methods to enhance the injection of electrons and we illustrate here one example where we have successfully achieved this by the introduction of a further, electron transport, layer. The result is an eight fold increase in efficiency over our best three layer PPV devices. The efficiency is also dependent on the details of the polymer electronic structure and using a family of copolymers we have been able to produce enhancements in efficiency to values of up to 30 times that of the corresponding PPV devices. Variations in the polymer electronic structure also affect the colour of emission and the same family of copolymers allow control of emission colour from blue/green to orange/red. Supramolecular control of the copolymer electronic structure can be achieved by lithographic patterning and we show that it is possible to produce regions within a single polymer film that possess different π-π* energy gaps.

Photophysics of light-emitting conjugated polymers

1993 ◽  
Author(s):  
Zoltan G. Soos ◽  
Douglas S. Galvao ◽  
S. Ramasesha ◽  
Shahab Etemad
Keyword(s):  
Conjugated Polymers ◽  
Light Emitting

Synthesis and optical properties of light-emitting π-conjugated polymers containing biphenyl and dithienosilole

2007 ◽  
Vol 45 (10) ◽  
pp. 2048-2058 ◽  
Author(s):  
Liang Liao ◽  
Ali Cirpan ◽  
Qinghui Chu ◽  
Frank E. Karasz ◽  
Yi Pang
Keyword(s):  
Optical Properties ◽  
Conjugated Polymers ◽  
Light Emitting
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