Prussian Blue Nanocontainers: Selectively Permeable Hollow Metal–Organic Capsules from Block Ionomer Emulsion-Induced Assembly

2011 ◽  
Vol 133 (22) ◽  
pp. 8420-8423 ◽  
Author(s):  
Xavier Roy ◽  
Joseph K.-H. Hui ◽  
Muhammad Rabnawaz ◽  
Guojun Liu ◽  
Mark J. MacLachlan
Keyword(s):  
Prussian Blue ◽  
Metal Organic ◽  
Block Ionomer ◽  
Hollow Metal

scholarly journals Mechanically Strong, Liquid-Resistant Photothermal Bioplastic Constructed from Cellulose and Metal-Organic Framework for Light-Driven Mechanical Motion

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4449
Author(s):  
Lijian Sun ◽  
Limei Li ◽  
Xianhui An ◽  
Xueren Qian
Keyword(s):  
Prussian Blue ◽  
Thermoelectric Generator ◽  
Metal Organic Framework ◽  
In Situ Synthesis ◽  
High Light ◽  
Hot Press ◽  
Mechanical Motion ◽  
Metal Organic ◽  
Organic Framework

The development of photothermal materials with a high light-to-heat conversion capability is essential for the utilization of clean solar energy. In this work, we demonstrate the use of a novel and sustainable concept involving cellulose liquefaction, rapid gelation, in situ synthesis and hot-press drying to convert cellulose and metal–organic framework (Prussian blue) into a stable photothermal bioplastic that can harvest sunlight and convert it into mechanical motion. As expected, the obtained Prussian blue@cellulose bioplastic (PCBP) can effectively absorb sunlight and the surface can be heated up to 70.3 °C under one sun irradiation (100 mW cm−2). As a demonstration of the practicality of PCBP, it was successfully used to drive a Stirling engine motion. Meanwhile, hot-pressing promotes the densification of the structure of PCBP and, therefore, improves the resistance to the penetration of water/non-aqueous liquids. Moreover, PCBP shows good mechanical properties and thermal stability. Given the excellent photothermal performance and environmentally friendly features of photothermal conversion bioplastic, we envisage this sustainable plastic film could play important roles toward diversified applications: a photothermal layer for thermoelectric generator, agricultural films for soil mulching and photothermal antibacterial activity, among others.

On-site evolution of ultrafine ZnO nanoparticles from hollow metal–organic frameworks for advanced lithium ion battery anodes

2017 ◽  
Vol 5 (43) ◽  
pp. 22512-22518 ◽  
Author(s):  
Yiqiong Zhang ◽  
Yanbing Lu ◽  
Shi Feng ◽  
Dongdong Liu ◽  
Zhaoling Ma ◽  
...  
Keyword(s):  
Current Density ◽  
Zno Nanoparticles ◽  
High Current Density ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
High Current ◽  
Metal Organic ◽  
Hollow Metal

With unique hollow frameworks decorated with well-dispersed ultrafine ZnO nanoparticles, the h-ZIF-8@ZnO hybrids exhibit good cycling performance with a reversible capacity of ∼637.9 mA h g−1 at a high current density of 1.0 A g−1 after 500 cycles.

Pristine hollow metal‐organic frameworks: design, synthesis and application

2020 ◽  
Author(s):  
Tianjie Qiu ◽  
Song Gao ◽  
Zibin Liang ◽  
De-Gao Wang ◽  
Hassina Tabassum ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Design Synthesis ◽  
Metal Organic ◽  
Hollow Metal

Hollow metal organic frameworks composite prepared via an “escape from the cage” strategy

2019 ◽  
Vol 240 ◽  
pp. 44-46 ◽  
Author(s):  
Yanmei Zhang ◽  
Xiang Zhang ◽  
Tianli Dai ◽  
Jun Li
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Hollow Metal

Hollow Metal–Organic Framework Microparticles Assembled via a Self-Templated Formation Mechanism

2015 ◽  
Vol 15 (11) ◽  
pp. 5169-5173 ◽  
Author(s):  
Ilrang Lee ◽  
Sora Choi ◽  
Hee Jung Lee ◽  
Moonhyun Oh
Keyword(s):  
Formation Mechanism ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Hollow Metal ◽  
Organic Framework

Flexible metal–organic frameworks as superior cathodes for rechargeable sodium-ion batteries

2015 ◽  
Vol 3 (32) ◽  
pp. 16590-16597 ◽  
Author(s):  
Ping Nie ◽  
Laifa Shen ◽  
Gang Pang ◽  
Yaoyao Zhu ◽  
Guiyin Xu ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Prussian Blue ◽  
Metal Organic Frameworks ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Prussian Blue Analogues ◽  
Ion Storage ◽  
Metal Organic ◽  
Flexible Metal ◽  
Sodium Ion Storage

Flexible metal–organic frameworks composed of Prussian blue analogues on a highly conductive carbonfiber paper have been synthesized and utilized as attractive hosts for sodium ion storage at ambient temperature.

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