Synthesis and Electronic Structure of Cationic, Neutral, and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single-Component Ethylene Polymerization Catalysts

2010 ◽  
Vol 132 (42) ◽  
pp. 15046-15059 ◽  
Author(s):  
Aaron M. Tondreau ◽  
Carsten Milsmann ◽  
Andrew D. Patrick ◽  
Helen M. Hoyt ◽  
Emil Lobkovsky ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Ethylene Polymerization ◽  
Single Component ◽  
Redox Activity ◽  
Polymerization Catalysts ◽  
Alkyl Complexes

Synthesis and Electronic Structure of Iron Borate Betaine Complexes as a Route to Single-Component Iron Ethylene Oligomerization and Polymerization Catalysts

2015 ◽  
Vol 34 (23) ◽  
pp. 5615-5623 ◽  
Author(s):  
Brian A. Schaefer ◽  
Grant W. Margulieux ◽  
Margaret A. Tiedemann ◽  
Brooke L. Small ◽  
Paul J. Chirik
Keyword(s):  
Electronic Structure ◽  
Single Component ◽  
Ethylene Oligomerization ◽  
Iron Borate ◽  
Polymerization Catalysts

Doubly fused N,N,N-Iron Ethylene Polymerization Catalysts appended with Fluoride Substituents; probing catalytic performance via a combined experimental and MLR study

2021 ◽  
Author(s):  
Qiuyue Zhang ◽  
Wenhong Yang ◽  
Zheng Wang ◽  
Gregory A. Solan ◽  
Tongling Liang ◽  
...  
Keyword(s):  
Ethylene Polymerization ◽  
Catalytic Performance ◽  
Chloride Complex ◽  
Polymerization Catalysts

Access to six examples of α,α’-bis(imino)-2,3:5,6-bis(pentamethylene)pyridine-iron(II) chloride complex, [2,3:5,6-{C4H8C(N(2-R1-4-R3-6-R2C6H2)}2C5HN] (R1 = Me, R2 = R3 = CH(p-FPh)2 Fe1; R1 = Et, R2 = R3 = CH(p-FPh)2 Fe2; R1 = iPr,...

Synthesis, Electronic Structure, and Ethylene Polymerization Activity of Bis(imino)pyridine Cobalt Alkyl Cations

2011 ◽  
Vol 123 (35) ◽  
pp. 8293-8297 ◽  
Author(s):  
Crisita Carmen Hojilla Atienza ◽  
Carsten Milsmann ◽  
Emil Lobkovsky ◽  
Paul J. Chirik
Keyword(s):  
Electronic Structure ◽  
Ethylene Polymerization ◽  
Alkyl Cations
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