Neutral Transition Metal Hydrides as Acids in Hydrogen Bonding and Proton Transfer: Media Polarity and Specific Solvation Effects

2010 ◽  
Vol 132 (32) ◽  
pp. 11234-11246 ◽  
Author(s):  
Vladislava A. Levina ◽  
Oleg A. Filippov ◽  
Evgenii I. Gutsul ◽  
Natalia V. Belkova ◽  
Lina M. Epstein ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Proton Transfer ◽  
Metal Hydrides ◽  
Specific Solvation ◽  
Solvation Effects ◽  
Transition Metal Hydrides

Modulation of quantum mechanical exchange couplings in transition metal hydrides rough hydrogen bonding

1997 ◽  
Vol 259 (1-2) ◽  
pp. 1-4 ◽  
Author(s):  
JoséA. Ayllon ◽  
Sylviane Sabo-Etienne ◽  
Bruno Chaudret ◽  
Stefan Ulrich ◽  
Hans-Heinrich Limbach
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Quantum Mechanical ◽  
Transition Metal Hydrides

Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η5-C5H5)M(CO)3H (M = Mo, W) and Bases

2006 ◽  
Vol 128 (11) ◽  
pp. 3486-3487 ◽  
Author(s):  
Natalia V. Belkova ◽  
Evgenii I. Gutsul ◽  
Oleg A. Filippov ◽  
Vladislava A. Levina ◽  
Dmitriy A. Valyaev ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Intermolecular Hydrogen Bonding ◽  
Transition Metal Hydrides

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation
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