Solid-State Photodecarbonylation of Diphenylcyclopropenone:  A Quantum Chain Process Made Possible by Ultrafast Energy Transfer

2008 ◽  
Vol 130 (4) ◽  
pp. 1140-1141 ◽  
Author(s):  
Gregory Kuzmanich ◽  
Arunkumar Natarajan ◽  
Khin K. Chin ◽  
Marcel Veerman ◽  
Christopher J. Mortko ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Chain Process ◽  
Quantum Chain

RADIATION-INDUCED CHANGES IN THE UNSATURATION OF POLYISOPRENE

1965 ◽  
Vol 43 (10) ◽  
pp. 2772-2785 ◽  
Author(s):  
Morton. A. Golub ◽  
Jeanne. Danon
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Benzene Solution ◽  
Chain Process ◽  
Energy Transfer Mechanism ◽  
Carbonium Ions ◽  
Intermolecular Energy ◽  
Radiation Induced ◽  
A Chain ◽  
Induced Changes

Polyisoprene in the solid state and in benzene solution undergoes radiation-induced cis-trans isomerization and loss of unsaturation. Starting with various cis or trans polymers, the isomerization approaches an equilibrium in which the cis/trans ratio is around 50/50 for polyisoprenes irradiated in solution or in the solid state. The G(isom.) values for either cis → trans or trans → cis isomerization, i.e., the number of cis (or trans) units isomerized initially per 100 eV absorbed by both polymer and solvent, in 1% solution, and by polymer alone, in the solid state, are about 1.0 and 10, respectively. The energy transfer mechanism proposed previously for polybutadiene and squalene isomerization is assumed to hold for polyisoprene as well. The loss of unsaturation in films irradiated with electrons under nitrogen is twice as rapid as in films γ-irradiated in vacuo, the G(-d.b.) (d.b. = double bond) values being 13.4 and 6.7, respectively. Correspondingly, G(-d.b.) for a γ-irradiated solution is 27, calculated in terms of energy absorbed directly by the polymer; intermolecular energy transfer is again indicated, although phenylation may also contribute to the loss of double bonds in solution. The large drop in unsaturation in solution and in the solid state is attributed to a chain process involving cyclization and some cross-linking, with the participation of both free radicals and carbonium ions. Work with polyisoprene-3-d confirmed the importance of isomerization and loss of unsaturation and gave an activation energy of 1.1 kcal/mole for the latter reaction.

Photoresponsive Frameworks: Energy Transfer in the Spotlight

2021 ◽  
Author(s):  
Corey R. Martin ◽  
Kyoung Chul Park ◽  
Ryan E. Corkill ◽  
Preecha Kittikhunnatham ◽  
Gabrielle A. Leith ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Covalent Organic Frameworks ◽  
Photochromic Behavior ◽  
Solid State Materials

In this paper, spiropyran-containing metal- and covalent-organic frameworks (MOFs and COFs, respectively) are probed as platforms for fostering photochromic behavior in solid-state materials while simultaneously promoting directional energy transfer (ET)....

scholarly journals Electrochemiluminescence Study of Europium (III) Complex with Coumarin3-Carboxylic Acid

2008 ◽  
Vol 2008 ◽  
pp. 1-6 ◽  
Author(s):  
Stefan Lis ◽  
Krzysztof Staninski ◽  
Tomasz Grzyb
Keyword(s):  
Aqueous Solution ◽  
Spectral Analysis ◽  
Energy Transfer ◽  
Solid State ◽  
Carboxylic Acid ◽  
Elemental Analysis ◽  
Aluminium Electrode ◽  
The Eu

The europium (III) complex of coumarin-3-carboxylic acid (C3CA) has been prepared and characterized on the basis of elemental analysis, IR, and emission (photoluminescence and electrochemiluminescence) spectroscopy. The synthesised complex having a formula Eu was photophysically characterized in solution and in the solid state. Electrochemiluminescence, ECL, of the system containing the Eu(III)/C3CA complex was studied using an oxide-covered aluminium electrode. The goal of these studies was to show the possibility of the use of electrochemical excitation of the Eu(III) ion in aqueous solution for emission generation. The generated ECL emission was very weak, and therefore its measurements and spectral analysis were carried out with the use of cut-off filters method. The studies proved a predominate role of the ligand-to-metal energy transfer (LMET) in the generated ECL.

Fluorescence modulation of a pyrazolone dye in the solid state based on energy transfer

2015 ◽  
Vol 39 (12) ◽  
pp. 9866-9871 ◽  
Author(s):  
Hu Liu ◽  
Ji-Xi Guo ◽  
Dian-Zeng Jia ◽  
Ming-Xi Guo ◽  
Lang Liu ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Fluorescence Modulation

A photochromic pyrazolone is exploited as a modulator to toggle the fluorescence of a dye “on” and “off” based on energy transfer.

Color tunable Ca8ZnM(PO4)7 (M = Lu/Tb, Lu/Eu, Tb/Eu) phosphors: luminescence, energy transfer and thermal stability studies for n-UV white LEDs

2021 ◽  
Author(s):  
Jing Yan ◽  
Chunyan Jiang ◽  
Yulun Xian ◽  
Jianbang Zhou ◽  
Hong Li ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Energy Transfer ◽  
High Temperature ◽  
Solid State ◽  
Powder Diffraction ◽  
Stability Studies ◽  
X Ray ◽  
White Leds ◽  
Color Tunable ◽  
Xrd Patterns

A series of Tb3+- and Eu3+-doped Ca8ZnLu(PO4)7 (CZLP:Tb3+ and CZLP:Eu3+) as well as Ca8ZnTb(PO4)7:Eu3+ (CZTP:Eu3+) phosphors have been prepared via the traditional high-temperature solid-state reaction. X-ray powder diffraction (XRD) patterns...

Optimization of concentration and length of laser medium in diode-end-pumped solid-state lasers considering energy-transfer-upconversion effects

Optik ◽  
2013 ◽  
Vol 124 (13) ◽  
pp. 1445-1449 ◽  
Author(s):  
Yaoting Wang ◽  
Wujun Li ◽  
Leilei Pan ◽  
Jintao Yu ◽  
Ruihong Zhang
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Laser Medium ◽  
Solid State Lasers ◽  
Energy Transfer Upconversion

A Study on the Luminescent Properties and Energy Transfer of Na2BaMgP2O8:Tb3+, Eu3+ Phosphor

2014 ◽  
Vol 700 ◽  
pp. 113-116
Author(s):  
Yu Jie Chen ◽  
Feng Lan Han ◽  
Zhao Luo
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Powder Diffraction ◽  
Luminescent Properties ◽  
Solid State Lighting ◽  
Diffraction Measurement ◽  
Effective Energy ◽  
X Ray ◽  
Red Color ◽  
Effective Energy Transfer

Na2BaMgP2O8phosphors were synthesized by a standard solid state reaction and their luminescent properties were investigated. The phase structure was analyzed by X-ray powder diffraction measurement. Under the excitation of 365nm, Na2BaMgP2O8:Tb3+, Eu3+phosphors show two color bands of green and red color due to5D4−7F5transition of Tb3+ions and5D0−7F2transition of Eu3+ions, respectively. The emission intensity of Tb3+deceased with the increasing concentration of Eu3+, which verified that an effective energy transfer occurred from Tb3+to Eu3+in Na2BaMgP2O8host. The present study indicated that the phosphors have a high potential application in solid state lighting.

scholarly journals Structure and photoluminescence properties of novel Sr6Ca4(PO4)6F2:Re (Re = Eu2+, Mn2+) phosphors with energy transfer for white-emitting LEDs

RSC Advances ◽  
2017 ◽  
Vol 7 (65) ◽  
pp. 41282-41288 ◽  
Author(s):  
Hongwei Xu ◽  
Lili Wang ◽  
Dan Qu ◽  
Zhiyun Si ◽  
Jinsheng Shi
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
White Light ◽  
Solid State Reaction ◽  
Photoluminescence Properties ◽  
Light Emitting

A series of Sr6Ca4(PO4)6F2:Eu2+,Mn2+ phosphors were synthesized by traditional solid state reaction. Through controlling the ratio of Eu2+ and Mn2+, emission colors can be tuned from blue to yellow, including white-light-emitting.

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