Electron-Deficient N-Heteroaromatic Linkers for the Elaboration of Large, Soluble Polycyclic Aromatic Hydrocarbons and Their Use in the Synthesis of Some Very Large Transition Metal Complexes

2007 ◽  
Vol 129 (38) ◽  
pp. 11743-11749 ◽  
Author(s):  
Yulia Fogel ◽  
Marcel Kastler ◽  
Zhaohui Wang ◽  
Denis Andrienko ◽  
Graham J. Bodwell ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Aromatic Hydrocarbons ◽  
Polycyclic Aromatic

scholarly journals A topological model for predicting adsorption energies of polycyclic aromatic hydrocarbons on late-transition metal surfaces

2019 ◽  
Vol 4 (2) ◽  
pp. 410-417
Author(s):  
Zhao-Bin Ding ◽  
Matteo Tommasini ◽  
Matteo Maestri
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Transition Metal ◽  
Aromatic Hydrocarbons ◽  
Topological Model ◽  
Late Transition Metal ◽  
Formation Enthalpies ◽  
Transition Metal Surfaces ◽  
Polycyclic Aromatic ◽  
Adsorption Energies ◽  
Late Transition

A topological model for the adsorption of PAHs is derived based on an analogy with the formation enthalpies of metal complexes.

ChemInform Abstract: Synthesis of Cyclohepta-1,3,5-trienes by Reaction of Aromatic Hydrocarbons with Diazo Compounds in the Presence of Transition Metal Complexes.

ChemInform ◽  
2010 ◽  
Vol 23 (50) ◽  
pp. no-no
Author(s):  
U. M. DZHEMILEV ◽  
V. A. DOKICHEV ◽  
S. Z. SULTANOV ◽  
R. A. SADYKOV ◽  
G. A. TOLSTIKOV ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Aromatic Hydrocarbons ◽  
Diazo Compounds

Oxidation of Polycyclic Aromatic Hydrocarbons with Hydrogen Peroxide in the Presence of Transition Metal Mono-Substituted Keggin-Type Polyoxometalates

ChemCatChem ◽  
2011 ◽  
Vol 3 (4) ◽  
pp. 771-779 ◽  
Author(s):  
Ana C. Estrada ◽  
Mário M. Q. Simões ◽  
Isabel C. M. S. Santos ◽  
M. Graça P. M. S. Neves ◽  
José A. S. Cavaleiro ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Transition Metal ◽  
Aromatic Hydrocarbons ◽  
Keggin Type ◽  
Polycyclic Aromatic

New interesting molecular topologies by way of modern cross-coupling reactions

2006 ◽  
Vol 78 (4) ◽  
pp. 813-830 ◽  
Author(s):  
Armin de Meijere ◽  
Baldur Stulgies ◽  
Karsten Albrecht ◽  
Karsten Rauch ◽  
Hermann A. Wegner ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Transition Metal ◽  
Aromatic Hydrocarbons ◽  
Cross Coupling ◽  
Spectroscopic Properties ◽  
Coupling Reactions ◽  
Highly Efficient ◽  
Cross Coupling Reactions ◽  
Polycyclic Aromatic ◽  
Metal Catalyzed

Modern transition-metal-catalyzed cross-coupling reactions, especially of the Kumada, Heck, and Suzuki types, have provided facile access to various bridge-annelated [2.2]paracyclophane derivatives including trifoliaphane and its tribenzo analog. The reduction of trifoliaphane with potassium metal in [D8]-THF led to hexakis[p-benzyl]benzene anion, which could efficiently be trapped with various electrophiles. Highly efficient multifold Suzuki couplings were performed with hexabromobenzene, octabromonaphthalene, and hexabromotriphenylene. The obtained hexa- and octaalkenylarene derivatives disclose interesting molecular shapes. Eventually, a newly developed cascade coupling of bromoarenes containing peri-positioned C-H bonds has led to indeno-annelated polycyclic aromatic hydrocarbons including indenocorannulene as well as the tetrakis- and tris(tert-butylindeno)pyrene which disclose very interesting spectroscopic properties. In particular, tetrakis(tert-butylindeno)pyrene self-assembles in solution by way of π-stacking, and it can be reduced with potassium metal to a stable dianion, a readily dimerizing trianion radical, and a tetraanion.

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