Room Temperature Hydroalkylation of Electron-Deficient Olefins:  sp3C−H Functionalization via a Lewis Acid-Catalyzed Intramolecular Redox Event

2005 ◽  
Vol 127 (35) ◽  
pp. 12180-12181 ◽  
Author(s):  
Stefan J. Pastine ◽  
Kevin M. McQuaid ◽  
Dalibor Sames
Keyword(s):  
Lewis Acid ◽  
Room Temperature ◽  
Acid Catalyzed

Lewis Acid Catalyzed Room-Temperature Michaelis–Arbuzov Rearrangement

2003 ◽  
Vol 42 (21) ◽  
pp. 2389-2392 ◽  
Author(s):  
Pierre-Yves Renard ◽  
Philippe Vayron ◽  
Eric Leclerc ◽  
Alain Valleix ◽  
Charles Mioskowski
Keyword(s):  
Lewis Acid ◽  
Room Temperature ◽  
Acid Catalyzed

scholarly journals Lewis Acid Catalyzed Room-Temperature Michaelis–Arbuzov Rearrangement

2003 ◽  
Vol 42 (34) ◽  
pp. 3981-3981
Author(s):  
Pierre-Yves Renard ◽  
Philippe Vayron ◽  
Eric Leclerc ◽  
Alain Valleix ◽  
Charles Mioskowski
Keyword(s):  
Lewis Acid ◽  
Room Temperature ◽  
Acid Catalyzed

Lewis Acid Catalyzed Room-Temperature Michaelis—Arbuzov Rearrangement.

ChemInform ◽  
2003 ◽  
Vol 34 (37) ◽  
Author(s):  
Pierre-Yves Renard ◽  
Philippe Vayron ◽  
Eric Leclerc ◽  
Alain Valleix ◽  
Charles Mioskowski
Keyword(s):  
Lewis Acid ◽  
Room Temperature ◽  
Acid Catalyzed

scholarly journals Lewis Acid Catalyzed Room-Temperature Michaelis–Arbuzov Rearrangement

2003 ◽  
Vol 115 (34) ◽  
pp. 4111-4111
Author(s):  
Pierre-Yves Renard ◽  
Philippe Vayron ◽  
Eric Leclerc ◽  
Alain Valleix ◽  
Charles Mioskowski
Keyword(s):  
Lewis Acid ◽  
Room Temperature ◽  
Acid Catalyzed

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) HomoDimers as Lewis Acidic Superelectrophiles

2018 ◽  
Author(s):  
Haley Albright ◽  
Paul S. Riehl ◽  
Christopher C. McAtee ◽  
Jolene P. Reid ◽  
Jacob R. Ludwig ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Olefin Metathesis ◽  
Acid Activation ◽  
Lewis Acid Catalysts ◽  
Distinct Mode ◽  
Aliphatic Ketones ◽  
Carbon Carbon Bond ◽  
Metathesis Reactions ◽  
Acid Catalyzed

<div>Catalytic carbonyl-olefin metathesis reactions have recently been developed as a powerful tool for carbon-carbon bond</div><div>formation. However, currently available synthetic protocols rely exclusively on aryl ketone substrates while the corresponding aliphatic analogs remain elusive. We herein report the development of Lewis acid-catalyzed carbonyl-olefin ring-closing metathesis reactions for aliphatic ketones. Mechanistic investigations are consistent with a distinct mode of activation relying on the in situ formation of a homobimetallic singly-bridged iron(III)-dimer as the active catalytic species. These “superelectrophiles” function as more powerful Lewis acid catalysts that form upon association of individual iron(III)-monomers. While this mode of Lewis acid activation has previously been postulated to exist, it has not yet been applied in a catalytic setting. The insights presented are expected to enable further advancement in Lewis acid catalysis by building upon the activation principle of “superelectrophiles” and broaden the current scope of catalytic carbonyl-olefin metathesis reactions.</div>

Naturally Occurring Organic Acid-catalyzed Facile Diastereoselective Synthesis of Biologically Active (E)-3-(arylimino)indolin-2-one Derivatives in Water at Room Temperature

2019 ◽  
Vol 23 (16) ◽  
pp. 1778-1788 ◽  
Author(s):  
Gurpreet Kaur ◽  
Arvind Singh ◽  
Kiran Bala ◽  
Mamta Devi ◽  
Anjana Kumari ◽  
...  
Keyword(s):  
Room Temperature ◽  
Biologically Active ◽  
Environmentally Benign ◽  
Diastereoselective Synthesis ◽  
Substituted Anilines ◽  
Reaction Conditions ◽  
Naturally Occurring ◽  
Acid Catalyzed ◽  
Reaction Media ◽  
Column Chromatographic

A simple, straightforward and efficient method has been developed for the synthesis of (E)-3-(arylimino)indolin-2-one derivatives and (E)-2-((4-methoxyphenyl)imino)- acenaphthylen-1(2H)-one. The synthesis of these biologically-significant scaffolds was achieved from the reactions of various substituted anilines and isatins or acenaphthaquinone, respectively, using commercially available, environmentally benign and naturally occurring organic acids such as mandelic acid or itaconic acid as catalyst in aqueous medium at room temperature. Mild reaction conditions, energy efficiency, good to excellent yields, environmentally benign conditions, easy isolation of products, no need of column chromatographic separation and the reusability of reaction media are some of the significant features of the present protocol.

scholarly journals Comparison of Corn Stover Pretreatments with Lewis Acid Catalyzed Choline Chloride, Glycerol and Choline Chloride-Glycerol Deep Eutectic Solvent

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1170
Author(s):  
Yuan Zhu ◽  
Benkun Qi ◽  
Xinquan Liang ◽  
Jianquan Luo ◽  
Yinhua Wan
Keyword(s):  
Corn Stover ◽  
Lewis Acid ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Enzymatic Saccharification ◽  
Glycerol Solution ◽  
Cellulose Conversion ◽  
Biomass Processing ◽  
Acid Catalyzed ◽  
Highly Correlated

Herein, corn stover (CS) was pretreated by less corrosive lewis acid FeCl3 acidified solutions of neat and aqueous deep eutectic solvent (DES), aqueous ChCl and glycerol at 120 °C for 4 h with single FeCl3 pretreatment as control. It was unexpected that acidified solutions of both ChCl and glycerol were found to be more efficient at removing lignin and xylan, leading to higher enzymatic digestibility of pretreated CS than acidified DES. Comparatively, acidified ChCl solution exhibited better pretreatment performance than acidified glycerol solution. In addition, 20 wt% water in DES dramatically reduced the capability of DES for delignification and xylan removal and subsequent enzymatic cellulose saccharification of pretreated CS. Correlation analysis showed that enzymatic saccharification of pretreated CS was highly correlated to delignification and cellulose crystallinity, but lowly correlated to xylan removal. Recyclability experiments of different acidified pretreatment solutions showed progressive decrease in the pretreatment performance with increasing recycling runs. After four cycles, the smallest decrease in enzymatic cellulose conversion (22.07%) was observed from acidified neat DES pretreatment, while the largest decrease (43.80%) was from acidified ChCl pretreatment. Those findings would provide useful information for biomass processing with ChCl, glycerol and ChCl-glycerol DES.

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