Divergent Kinetic Control of Classical versus Ozonolytic Lactonization:  Mechanism-Based Diastereoselection

2005 ◽  
Vol 127 (23) ◽  
pp. 8256-8257 ◽  
Author(s):  
Thomas R. Hoye ◽  
Troy D. Ryba
Keyword(s):  
Kinetic Control

Trypsin entrapped within liposomes. Partition of a low-molecular-mass substrate as the main factor in kinetic control of hydrolysis

1991 ◽  
Vol 56 (3) ◽  
pp. 712-717 ◽  
Author(s):  
Jana Formelová ◽  
Albert Breier ◽  
Peter Gemeiner ◽  
Lubica Kurillová
Keyword(s):  
Molecular Mass ◽  
Egg Yolk ◽  
Kinetic Control ◽  
Hydrolysis Kinetics ◽  
Liposomal Membrane ◽  
Kinetics Of ◽  
Main Factor

Trypsin has been entrapped within liposomes prepared from egg yolk phospholipides by the method of controlled dialysis, and the hydrolysis kinetics of Nα-benzoyl-DL-arginine p-nitroaniline catalyzed by the liposome-entrapped trypsin has been studied by monitoring the flux of substrate and product across the liposomal membrane. The partitioning of the substrate and product between liposomal and extraliposomal environment has been found to represent the main factor in the kinetic control of the hydrolysis.

Kinetic Control of Length and Morphology of Segmented Polymeric Nanofibers in Microfluidic Chips

Langmuir ◽  
2020 ◽  
Vol 36 (44) ◽  
pp. 13364-13370
Author(s):  
Zhengping Tan ◽  
Zaiyan Hou ◽  
Ke Wang ◽  
Yuce Li ◽  
Lianbin Zhang ◽  
...  
Keyword(s):  
Kinetic Control ◽  
Microfluidic Chips ◽  
Polymeric Nanofibers

scholarly journals Near quantitative synthesis of urea macrocycles enabled by bulky N-substituent

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yingfeng Yang ◽  
Hanze Ying ◽  
Zhixia Li ◽  
Jiang Wang ◽  
Yingying Chen ◽  
...  
Keyword(s):  
High Efficiency ◽  
Molecular Structures ◽  
High Yield ◽  
Kinetic Control ◽  
High Concentration ◽  
Weak Association ◽  
Quantitative Synthesis ◽  
Thermodynamic Stabilization ◽  
Discrete Structures ◽  
Very High

AbstractMacrocycles are unique molecular structures extensively used in the design of catalysts, therapeutics and supramolecular assemblies. Among all reactions reported to date, systems that can produce macrocycles in high yield under high reaction concentrations are rare. Here we report the use of dynamic hindered urea bond (HUB) for the construction of urea macrocycles with very high efficiency. Mixing of equal molar diisocyanate and hindered diamine leads to formation of macrocycles with discrete structures in nearly quantitative yields under high concentration of reactants. The bulky N-tert-butyl plays key roles to facilitate the formation of macrocycles, providing not only the kinetic control due to the formation of the cyclization-promoting cis C = O/tert-butyl conformation, but also possibly the thermodynamic stabilization of macrocycles with weak association interactions. The bulky N-tert-butyl can be readily removed by acid to eliminate the dynamicity of HUB and stabilize the macrocycle structures.

Growth kinetic control over MgFe2O4 to tune Fe occupancy and metal–support interactions for optimum catalytic performance

CrystEngComm ◽  
2021 ◽  
Vol 23 (13) ◽  
pp. 2538-2546
Author(s):  
Min Yang ◽  
Guangshe Li ◽  
Huixia Li ◽  
Junfang Ding ◽  
Yan Wang ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Growth Kinetic ◽  
Catalytic Performance ◽  
Growth Behavior ◽  
Kinetic Control ◽  
Size Dependent ◽  
Metal Support ◽  
Support Size ◽  
Metal Support Interactions ◽  
First Time

For the first time, the growth behavior with size-dependent Fe occupancies at different sites of MgFe2O4 was examined. Hybrid catalysts of Pt/MgFe2O4 with a support size of 20.6 nm exhibited an optimal performance of CO oxidation.

Kinetic Control of O2 Reactivity in H-NOX Domains

2016 ◽  
Vol 120 (24) ◽  
pp. 5351-5358 ◽  
Author(s):  
Yuhan Sun ◽  
Abdelkrim Benabbas ◽  
Weiqiao Zeng ◽  
Sandhya Muralidharan ◽  
Elizabeth M. Boon ◽  
...  
Keyword(s):  
Kinetic Control

Color-Tunable ZnO Quantum Dots Emitter: Size Effect Study and a Kinetic Control of Crystallization

2013 ◽  
Vol 2 (1) ◽  
pp. 11-19 ◽  
Author(s):  
Chengbo Zhang ◽  
Shihong Zhou ◽  
Keyan Li ◽  
Shuyan Song ◽  
Dongfeng Xue
Keyword(s):  
Quantum Dots ◽  
Size Effect ◽  
Effect Study ◽  
Kinetic Control ◽  
Color Tunable ◽  
Zno Quantum Dots

scholarly journals Dual-stimuli pseudorotaxane switches under kinetic control

2021 ◽  
Author(s):  
Marius Gaedke ◽  
Henrik Hupatz ◽  
Hendrik V. Schröder ◽  
Simon Suhr ◽  
Kurt F. Hoffmann ◽  
...  
Keyword(s):  
Ammonium Salts ◽  
Kinetic Control

A series of dumbbell-shaped sec-ammonium salts with bulky (pseudo)stoppers (‘speed bumps’) were tested for their ability to form pseudorotaxanes with a redox-switchable, tetrathiafulvalene (TTF)-decorated [24]crown-8 ether. Depending on the size...

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