Determination of Molecular Structure in Solution Using Vibrational Circular Dichroism Spectroscopy:  the Supramolecular Tetramer ofS -2,2‘-Dimethyl-Biphenyl-6,6‘-Dicarboxylic Acid

2005 ◽  
Vol 127 (18) ◽  
pp. 6700-6711 ◽  
Author(s):  
M. Urbanová ◽  
V. Setnička ◽  
F. J. Devlin ◽  
P. J. Stephens
Keyword(s):  
Molecular Structure ◽  
Circular Dichroism ◽  
Dicarboxylic Acid ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
Circular Dichroïsm ◽  
Structure In Solution

Determination of Enantiomeric Excess in Deuterated Chiral Hydrocarbons by Vibrational Circular Dichroism Spectroscopy

1990 ◽  
Vol 44 (2) ◽  
pp. 235-238 ◽  
Author(s):  
Kevin M. Spencer ◽  
Steven J. Cianciosi ◽  
John E. Baldwin ◽  
Teresa B. Freedman ◽  
Laurence A. Nafie
Keyword(s):  
Circular Dichroism ◽  
Enantiomeric Excess ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
Circular Dichroïsm

scholarly journals VCD Determination of the Absolute Configuration of Stypotriol

2009 ◽  
Vol 4 (8) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Marcelo A. Muñoz ◽  
Carlos Areche ◽  
Aurelio San-Martín ◽  
Juana Rovirosa ◽  
Pedro Joseph-Nathan
Keyword(s):  
Circular Dichroism ◽  
Natural Product ◽  
Absolute Configuration ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
Stypopodium Zonale ◽  
The Absolute ◽  
Circular Dichroïsm

The absolute configuration of the pentacyclic ichthyotoxin stypotriol, a constituent of Stypopodium zonale, was deduced to be 3S,5R,8R,9R,10S,13S,14S-(-)-1 by vibrational circular dichroism spectroscopy of the derived triacetate 2 in comparison to DFT B3LYP/DGDZVP calculations. Compound 2, C33H46O7 having 300 electrons, is the largest natural product successfully studied by VCD to date.

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