Cavity-Induced Spin−Spin Interaction between Organic Radicals within a Self-Assembled Coordination Cage

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Makoto Fujita
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Makoto Fujita

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Makoto Fujita

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Dmitri V. Belykh

Results of the study of Mn (II)/Mn (III)-NEt3 complex self-assembled with the formation of hydrophobic core are considered in terms of hydrogen bonding between the ligands of manganese octahedral complexes. It is found that the hydrogen bonding plays important role in spin-spin interaction of the coupled Mn-aquacomplexes. Number of H2O molecules in the shell of the latter is suggested to estimate according to the peak-to-peak width (ΔBpp) of the broadened ESR pattern.


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