Ionic Liquids by Proton Transfer:  Vapor Pressure, Conductivity, and the Relevance of ΔpKafrom Aqueous Solutions

2003 ◽  
Vol 125 (50) ◽  
pp. 15411-15419 ◽  
Author(s):  
Masahiro Yoshizawa ◽  
Wu Xu ◽  
C. Austen Angell
Keyword(s):  
Ionic Liquids ◽  
Vapor Pressure ◽  
Proton Transfer ◽  
Aqueous Solutions

scholarly journals Extremely Low Vapor‐Pressure Data as Access to PC‐SAFT Parameter Estimation for Ionic Liquids and Modeling of Precursor Solubility in Ionic Liquids

ChemistryOpen ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 216-226
Author(s):  
Mark Bülow ◽  
Moritz Greive ◽  
Dzmitry H. Zaitsau ◽  
Sergey P. Verevkin ◽  
Christoph Held
Keyword(s):  
Parameter Estimation ◽  
Ionic Liquids ◽  
Vapor Pressure ◽  
Pressure Data ◽  
Vapor Pressure Data

scholarly journals Enhancing Artemisinin Solubility in Aqueous Solutions: Searching for Hydrotropes based on Ionic Liquids

2021 ◽  
Vol 534 ◽  
pp. 112961
Author(s):  
Isabela Sales ◽  
Dinis O. Abranches ◽  
Pedro Costa ◽  
Tânia E. Sintra ◽  
Sónia P.M. Ventura ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Aqueous Solutions

Adsorption of imidazolium-based ionic liquids with different chemical structures onto various resins from aqueous solutions

RSC Advances ◽  
2015 ◽  
Vol 5 (52) ◽  
pp. 41352-41358 ◽  
Author(s):  
Luyang Li ◽  
Yu Wang ◽  
Xinhua Qi
Keyword(s):  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Adsorption Behavior ◽  
Chemical Structures

The adsorption behavior of a series of imidazolium-based ionic liquids with different chemical structures onto various resins was investigated.

scholarly journals Valorization of Spent Coffee by Caffeine Extraction Using Aqueous Solutions of Cholinium-Based Ionic Liquids

2021 ◽  
Vol 13 (13) ◽  
pp. 7509
Author(s):  
Ana M. Ferreira ◽  
Hugo M. D. Gomes ◽  
João A. P. Coutinho ◽  
Mara G. Freire
Keyword(s):  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Pure Water ◽  
Waste Product ◽  
Weight Ratio ◽  
Extraction Yield ◽  
Operational Conditions ◽  
Coffee Grounds ◽  
Extractable Compounds ◽  
Nutraceutical Products

Spent coffee grounds (SCGs) are a waste product with no relevant commercial value. However, SCGs are rich in extractable compounds with biological activity. To add value to this coffee byproduct, water and aqueous solutions of cholinium-based ionic liquids (ILs) were studied to extract caffeine from SCGs. In general, all IL aqueous solutions lead to higher extraction efficiencies of caffeine than pure water, with aqueous solutions of cholinium bicarbonate being the most efficient. A factorial planning was applied to optimize operational conditions. Aqueous solutions of cholinium bicarbonate, at a temperature of 80 °C for 30 min of extraction, a biomass–solvent weight ratio of 0.05 and at an IL concentration of 1.5 M, made it possible to extract 3.29 wt% of caffeine (against 1.50 wt% obtained at the best conditions obtained with pure water). Furthermore, to improve the sustainability of the process, the same IL aqueous solution was consecutively applied to extract caffeine from six samples of fresh biomass, where an increase in the extraction yield from 3.29 to 13.10 wt% was achieved. Finally, the cholinium bicarbonate was converted to cholinium chloride by titration with hydrochloric acid envisioning the direct application of the IL-caffeine extract in food, cosmetic and nutraceutical products. The results obtained prove that aqueous solutions of cholinium-based ILs are improved solvents for the extraction of caffeine from SCGs, paving the way for their use in the valorization of other waste rich in high-value compounds.

Sign in / Sign up

Export Citation Format

Share Document