Inner-Sphere Electron-Transfer Reorganization Energies of Zinc Porphyrins

2004 ◽  
Vol 126 (47) ◽  
pp. 15566-15571 ◽  
Author(s):  
Xenia Amashukeli ◽  
Nadine E. Gruhn ◽  
Dennis L. Lichtenberger ◽  
Jay R. Winkler ◽  
Harry B. Gray
Keyword(s):  
Electron Transfer ◽  
Inner Sphere ◽  
Zinc Porphyrins ◽  
Reorganization Energies

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO2 via Through‐Space Electronic Conjugation

2021 ◽  
Author(s):  
Shelby L. Hooe ◽  
Juan J. Moreno ◽  
Amelia G. Reid ◽  
Emma N. Cook ◽  
Charles Machan
Keyword(s):  
Electron Transfer ◽  
Homogeneous Reduction ◽  
Inner Sphere ◽  
Reduction Of Co2
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