Effect of Catalysis on the Stability of Metallic Nanoparticles:  Suzuki Reaction Catalyzed by PVP-Palladium Nanoparticles

2003 ◽  
Vol 125 (27) ◽  
pp. 8340-8347 ◽  
Author(s):  
Radha Narayanan ◽  
Mostafa A. El-Sayed
Keyword(s):  
Palladium Nanoparticles ◽  
Metallic Nanoparticles ◽  
Suzuki Reaction ◽  
The Stability

scholarly journals PREPARATION AND STABILITY OF SILVER AND PALLADIUM NANOPARTICLES STABILIZED BY POLYETHER LAPROL 5003 IN N,N – DIMETHYLFORMAMIDE MEDIA

2019 ◽  
Vol 62 (5) ◽  
pp. 50-55
Author(s):  
Alexander V. Bespalov ◽  
Yana O. Ivanova
Keyword(s):  
Palladium Nanoparticles ◽  
Metallic Nanoparticles ◽  
Potassium Thiocyanate ◽  
Reducing Agent ◽  
Spectral Studies ◽  
Optical Absorption Spectroscopy ◽  
Absorption Bands ◽  
The Stability ◽  
Average Size ◽  
Silver Cations

This paper is devoted to obtaining and investigating the stability of silver and palladium sols in N,N-dimethylformamide medium. Due to the unique properties exhibited by metals in the nanosized state, metallic nanoparticles are gaining increasing importance in various fields of application, science and technology. This makes the task of obtaining stable metal sols extremely urgent. The synthesis of aggregate-resistant organosols of metals is associated with a number of problems, since the metal sols obtained in organic media are much less stable than hydrosols. For this reason, there arises the challenge of choosing an appropriate stabilizer. In this study, the stabilizer was branched polyester Laprol 5003. A distinctive feature of the synthesis of silver sols was the absence of a special reducing agent, since N,N-dimethylformamide, used as a solvent, recovers silver cations  itself. As a result, stable sols of silver and palladium have been obtained in N,N-dimethylformamide medium. Sodium borohydride was used as the reducing agent for the synthesis of palladium nanoparticles. Spectral studies of the resulting sols were carried out. The silver and palladium nanoparticles were sized up by scanning electron microscopy. The procedure has shown that the average size of the silver particles formed in the N,N-dimethylformamide medium is 4 ± 2 nm, which is substantially smaller than the particles obtained in isopropanol medium by the borohydride method.  The silver sols aggregation in dimethylformamide under the action of potassium thiocyanate was studied via optical absorption spectroscopy. It has been found that the stability of the silver sol in dimethylformamide to the electrolyte is higher than that of the sol obtained in isopropanol. It has also been detected that several absorption bands are present in the optical spectrum of the palladium sol in dimethylformamide. The effect of the stabilizing polyester concentration on the stability of silver and palladium sols in N,N-dimethylformamide was studied. The result is that when the concentration of Laprol 5003 exceeds some quantity, a sharp increase in the aggregation time of sols is observed, which indicates a significant increase in their stability.

Immobilized Palladium nanoparticles on phosphanamine-grafted cellulose for arylation of uracil

2021 ◽  
Vol 08 ◽  
Author(s):  
Qian Yang ◽  
Na Ma ◽  
Yangqing He ◽  
Xiaojiao Yu ◽  
Binghua Yao
Keyword(s):  
Palladium Nanoparticles ◽  
Suzuki Reaction ◽  
Boronic Acids ◽  
Efficient Catalyst ◽  
Cellulose Material

Background: The synthesis of 5-arylation uracil nucleosides is an imperative challenge. Especially for the method of suzuki reaction using N-unprotected uracil as materials, which holds potential to enhance the yield. Objective: In order to find a more efficient catalyst to increase the yield of aryluracils and aryluridines. Methods: We first constructed the phosphanamine-grafted cellulose (PAGC) from cellulose material. And then prepared the nanocatalyst PAGC/Pd(0) through heating and reducing the mixture of PAGC and Pa(OAc)2. Results: When using this nanocatalyst to catalyze the Suzuki reaction of 5-iodouracil or 5-iodouridine and aryl heterocyclic boronic acids. The arylation yields have been a significantly improvement. Conclusion: This means that the resultant nanocatalyst exhibits a remarkable catalytic efficacy for Suzuki arylation of 5-iodouracil and 5-iodouridine.

ChemInform Abstract: Bio-Supported Palladium Nanoparticles as a Phosphine-Free Catalyst for the Suzuki Reaction in Water.

ChemInform ◽  
2012 ◽  
Vol 43 (29) ◽  
pp. no-no
Author(s):  
Peipei Zhou ◽  
Huanhuan Wang ◽  
Jiazhi Yang ◽  
Jian Tang ◽  
Dongping Sun ◽  
...  
Keyword(s):  
Palladium Nanoparticles ◽  
Suzuki Reaction ◽  
Supported Palladium ◽  
Reaction In Water
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