From readily accessible arylhydrazines and allyloxyketones, 2,2-disubstituted indolin-3-ones could be obtained in good to excellent yields via a cascade Fischer indolization/Claisen rearrangement process.
We examined the possible effect microwaves may have on intramolecular reactions such as the Claisen-type rearrangement process carried out in DMSO solvent and in solvent-free microwave irradiation conditions.