Catalytic Asymmetric Reductive Coupling of Alkynes and Aldehydes:  Enantioselective Synthesis of Allylic Alcohols and α-Hydroxy Ketones

2003 ◽  
Vol 125 (12) ◽  
pp. 3442-3443 ◽  
Author(s):  
Karen M. Miller ◽  
Wei-Sheng Huang ◽  
Timothy F. Jamison
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Alcohols ◽  
Reductive Coupling ◽  
Hydroxy Ketones ◽  
Catalytic Asymmetric

Scope and limitations of the catalytic asymmetric rearrangement of epoxides to allylic alcohols using chiral lithium amide bases/lithiated imidazoles

2005 ◽  
Vol 46 (48) ◽  
pp. 8315-8318 ◽  
Author(s):  
Sally J. Oxenford ◽  
Jonathan M. Wright ◽  
Peter O’Brien ◽  
Narendra Panday ◽  
Mark R. Shipton
Keyword(s):  
Allylic Alcohols ◽  
Lithium Amide ◽  
Catalytic Asymmetric

scholarly journals Enantioselective synthesis of (−)-chloramphenicol via silver-catalysed asymmetric isocyanoacetate aldol reaction

2016 ◽  
Vol 14 (1) ◽  
pp. 93-96 ◽  
Author(s):  
Allegra Franchino ◽  
Pavol Jakubec ◽  
Darren J. Dixon
Keyword(s):  
Aldol Reaction ◽  
Enantioselective Synthesis ◽  
Asymmetric Aldol ◽  
Asymmetric Aldol Reaction ◽  
Catalytic Asymmetric

A concise synthesis of (−)-chloramphenicol, based on the catalytic asymmetric aldol reaction between 4-nitrobenzaldehyde and benzhydryl isocyanoacetate, is reported.

Sign in / Sign up

Export Citation Format

Share Document