Microwave Spectra and Structures of KrAuF, KrAgF, and KrAgBr;83Kr Nuclear Quadrupole Coupling and the Nature of Noble Gas−Noble Metal Halide Bonding

2004 ◽  
Vol 126 (4) ◽  
pp. 1235-1246 ◽  
Author(s):  
Jason M. Thomas ◽  
Nicholas R. Walker ◽  
Stephen A. Cooke ◽  
Michael C. L. Gerry
Keyword(s):  
Noble Metal ◽  
Noble Gas ◽  
Metal Halide ◽  
Microwave Spectra ◽  
Quadrupole Coupling ◽  
Nuclear Quadrupole

Mikrowellenspektrum und rotationsspektroskopische Konstanten der Methylchlorsilane: CH3SiH2Cl, CH3SiD2Cl und CD3SiD2Cl / Microwave Spectrum and Rotational Spectroscopic Constants of Methyl-chloro-silane: CH3SiH2Cl, CH3SiD2Cl and CD3SiD2Cl

1975 ◽  
Vol 30 (11) ◽  
pp. 1441-1446
Author(s):  
W. Zeil ◽  
W. Braun ◽  
B. Haas ◽  
H. Knehr ◽  
F. Rückert ◽  
...  
Keyword(s):  
Microwave Spectrum ◽  
Coupling Constants ◽  
Spectroscopic Constants ◽  
Centrifugal Distortion ◽  
Rotational Constants ◽  
Microwave Spectra ◽  
Isotopic Species ◽  
Quadrupole Coupling ◽  
Nuclear Quadrupole ◽  
Centrifugal Distortion Constants

The microwave spectra of the following isotopic species of Methyl-chloro-silane: CH3SiH2Cl, CH3SiD2 and CD3SiD2Cl have been measured and the rotational spectroscopic constants (rotational constants, centrifugal distortion constants and nuclear quadrupole coupling constants) have been determined

Nitrogen Quadrupole Coupling in the Microwave Spectra of Phenyl Isocyanate and Phenyl Isothiocyanate

1987 ◽  
Vol 42 (1) ◽  
pp. 79-82 ◽  
Author(s):  
W. Kasten ◽  
H. Dreizler
Keyword(s):  
Fourier Transform ◽  
Hyperfine Splitting ◽  
Fourier Transform Spectroscopy ◽  
Phenyl Isocyanate ◽  
Phenyl Isothiocyanate ◽  
Microwave Spectra ◽  
Quadrupole Coupling ◽  
Nuclear Quadrupole

The microwave spectra of phenyl isocyanate, C6H5NCO, and phenyl isothiocyanate, C6H5NCS, have been measured by microwave Fourier transform spectroscopy between 4.7 and 8.0 GHz and analysed for nuclear quadrupole hyperfine splitting due to 14N.

Mikrowellenspektrum, Rotationskonstanten, Zentrifugalverzerrungskonstanten und Kernquadrupolkopplungskonstanten des CD3SiH2Cl. Über Bindungseigenschaften in Silicium-Halogeniden: 1. Mitteilung / Microwave spectrum, rotational constants, centrifugaldistortion constants and nuclear quadrupole coupling constants of CD3SiH2Cl

1972 ◽  
Vol 27 (7) ◽  
pp. 1150-1159 ◽  
Author(s):  
Werner Zeil ◽  
Richard Gegenheimer ◽  
Saskia Pferrer ◽  
Marwan Dakkouri
Keyword(s):  
Microwave Spectrum ◽  
Coupling Constants ◽  
Rotational Constants ◽  
Microwave Spectra ◽  
Isotopic Species ◽  
Quadrupole Coupling ◽  
Nuclear Quadrupole

Abstract Microwave The microwave spectra of the following isotopic species of methylchloro-silane CD328SiH235Cl, CD329SiH235Cl, CD330SiH235Cl, CD328SiH237Cl have been measured and analyzed. The rotational constants, centrifugaldistortion constants and nuclear quadrupole coupling constants have been determined. The Si-Cl-distance is 2.049 Å respectively 2.052 Å as calculated by the rs method. The corresponding angles between the siliconchlorine-bond and the inertia-axis a are Θ = 26°53' respectively 26°49'

The Microwave Spectra and Nitrogen Quadrupole Coupling Constants of Cyano- and Isocyano-pentafluorobenzene

1992 ◽  
Vol 47 (7-8) ◽  
pp. 865-868 ◽  
Author(s):  
Michael Krüger ◽  
Helmut Dreizler
Keyword(s):  
Fourier Transform ◽  
Molecular Beam ◽  
Fourier Transform Spectroscopy ◽  
Coupling Constants ◽  
Microwave Spectra ◽  
Quadrupole Coupling ◽  
Nuclear Quadrupole

Abstract The microwave spectra of cyano-pentafluorobenzene, C6F5CN, and isocyano-pentafluorobenzene, C6F5NC , have been assigned by molecular beam microwave Fourier transform spectroscopy. The 14N nuclear quadrupole coupling constants have been determined for both isomers

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