A Highly Reduced V23+Unit with a Metal−Metal Bond Order of 3.5

2003 ◽  
Vol 125 (8) ◽  
pp. 2026-2027 ◽  
Author(s):  
F. Albert Cotton ◽  
Elizabeth A. Hillard ◽  
Carlos A. Murillo
Keyword(s):  
Bond Order ◽  
Metal Bond ◽  
Metal Metal

Systematic Variation of Metal–Metal Bond Order in Metal–Chromium Complexes

2013 ◽  
Vol 135 (35) ◽  
pp. 13142-13148 ◽  
Author(s):  
Laura J. Clouston ◽  
Randall B. Siedschlag ◽  
P. Alex Rudd ◽  
Nora Planas ◽  
Shuxian Hu ◽  
...  
Keyword(s):  
Bond Order ◽  
Systematic Variation ◽  
Chromium Complexes ◽  
Metal Bond ◽  
Metal Metal

Palladium(ii)–palladium(ii) bonding in two open clamshell dinuclear complexes

2017 ◽  
Vol 41 (15) ◽  
pp. 7384-7391 ◽  
Author(s):  
Shanti G. Patra ◽  
Nirmal K. Shee ◽  
Michael G. B. Drew ◽  
Dipankar Datta
Keyword(s):  
Bond Order ◽  
Dinuclear Complexes ◽  
Metal Bond ◽  
Metal Metal

In two Pd(ii) dimers with Pd–Pd distance ≤3.26 Å, the metal–metal bond order is found to be zero.

scholarly journals Malcolm Harold Chisholm. 15 October 1945 — 20 November 2015

2016 ◽  
Vol 63 ◽  
pp. 117-136
Author(s):  
Richard J. Puddephatt
Keyword(s):  
Organic Compounds ◽  
Bond Order ◽  
Functional Materials ◽  
Synthetic Chemistry ◽  
Great Pleasure ◽  
Metal Bond ◽  
Triple Bonds ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Malcolm Chisholm was one of the most creative and distinguished inorganic chemists of his generation. He was particularly renowned for his chemistry of compounds containing multiple metal–metal bonds and for showing how they could give insights into catalysis or be used in functional materials. Very early in his independent career he reported the remarkable compounds M 2 X 6 , with M = molybdenum or tungsten and X = alkoxide or dialkylamide, which contain metal–metal triple bonds, and his group showed how they could activate organic compounds in unusual ways, often with changes in the metal–metal bond order. He was a master of synthetic chemistry, but he also made notable discoveries in theory, spectroscopy and catalysis. Personally, he was outgoing, friendly and fun-loving. He was faithful and supportive of his family, students, colleagues and his many friends around the globe, and took great pleasure in their successes.

scholarly journals Systematic variation of metal--metal bond order in metalloporphyrin dimers

1983 ◽  
Vol 80 (24) ◽  
pp. 7684-7688 ◽  
Author(s):  
J. P. Collman ◽  
C. E. Barnes ◽  
L. K. Woo
Keyword(s):  
Bond Order ◽  
Systematic Variation ◽  
Metal Bond ◽  
Metal Metal
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