Low-Temperature NMR Studies of the Structure and Dynamics of a Novel Series of Acid−Base Complexes of HF with Collidine Exhibiting Scalar Couplings Across Hydrogen Bonds†

2003 ◽  
Vol 125 (38) ◽  
pp. 11710-11720 ◽  
Author(s):  
Ilja G. Shenderovich ◽  
Peter M. Tolstoy ◽  
Nikolai S. Golubev ◽  
Sergei N. Smirnov ◽  
Gleb S. Denisov ◽  
...  
Keyword(s):  
Low Temperature ◽  
Hydrogen Bonds ◽  
Scalar Couplings ◽  
Acid Base ◽  
Nmr Studies ◽  
Structure And Dynamics

Molecular Structure and Dynamics in Organic Solids: High Resolution Low Temperature 13 C NMR Studies

1983 ◽  
Vol 96 (1) ◽  
pp. 305-317 ◽  
Author(s):  
Costantino S. Yannoni ◽  
Thomas C. Clarke ◽  
Raymond D. Kendrick ◽  
Volker Macho ◽  
Robert D. Miller ◽  
...  
Keyword(s):  
Molecular Structure ◽  
High Resolution ◽  
Low Temperature ◽  
Nmr Studies ◽  
Organic Solids ◽  
Structure And Dynamics ◽  
C Nmr

Correlation of Protein Structure and Dynamics to Scalar Couplings across Hydrogen Bonds

2007 ◽  
Vol 129 (18) ◽  
pp. 5898-5903 ◽  
Author(s):  
Hans-Jürgen Sass ◽  
Franziska Fang-Fang Schmid ◽  
Stephan Grzesiek
Keyword(s):  
Protein Structure ◽  
Hydrogen Bonds ◽  
Scalar Couplings ◽  
Structure And Dynamics ◽  
Protein Structure And Dynamics

Structure and Dynamics of the Golgi Complex at 15 oC: Low Temperature Induces the Formation of Golgi-Derived Tubules

Traffic ◽  
2005 ◽  
Vol 6 (1) ◽  
pp. 32-44 ◽  
Author(s):  
Emma Martinez-Alonso ◽  
Gustavo Egea ◽  
Jose Ballesta ◽  
Jose A. Martinez-Menarguez
Keyword(s):  
Low Temperature ◽  
Golgi Complex ◽  
Structure And Dynamics

Detection of Scalar Couplings Across NH···OP and OH···OP Hydrogen Bonds in a Flavoprotein

2000 ◽  
Vol 122 (38) ◽  
pp. 9289-9295 ◽  
Author(s):  
Frank Löhr ◽  
Stephen G. Mayhew ◽  
Heinz Rüterjans
Keyword(s):  
Hydrogen Bonds ◽  
Scalar Couplings

Infrared spectra of the ammonium ion in crystals. Part VIII. Spectroscopic criteria of highly-bent hydrogen bonds

1980 ◽  
Vol 58 (9) ◽  
pp. 867-874 ◽  
Author(s):  
Osvald Knop ◽  
Wolfgang J. Westerhaus ◽  
Michael Falk
Keyword(s):  
Low Temperature ◽  
Hydrogen Bonds ◽  
Infrared Spectra ◽  
Room Temperature ◽  
Ammonium Ion ◽  
Temperature Transition ◽  
Increasing Temperature

Available evidence suggests that (1) the stretching frequencies of highly-bent hydrogen bonds decrease with increasing temperature, regardless of whether the bonds are static or dynamic in character, to a single acceptor or to several competing acceptors; and (2) departures from symmetric trifurcation (or bifurcation) toward asymmetric situations lower the stretching frequency. In further support of these criteria isotopic probe ion spectra between 10 K and room temperature have been obtained for taurine and for trigonal (NH4)2MF6 (M = Si, Ge, Sn, Ti). Evidence of a low-temperature transition at 100(10) K in trigonal (NH4)2SnF6 is presented, and existence of the previously reported transition at 38.6 K in trigonal (NH4)2SiF6 is confirmed. Symmetry changes associated with these transitions are discussed.

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