Copper-Catalyzed Halogen Exchange in Aryl Halides:  An Aromatic Finkelstein Reaction

2002 ◽  
Vol 124 (50) ◽  
pp. 14844-14845 ◽  
Author(s):  
Artis Klapars ◽  
Stephen L. Buchwald
Keyword(s):  
Aryl Halides ◽  
Halogen Exchange

scholarly journals Copper-Catalyzed Halogen Exchange in Aryl Halides: An Aromatic Finkelstein Reaction.

ChemInform ◽  
2003 ◽  
Vol 34 (17) ◽  
Author(s):  
Artis Klapars ◽  
Stephen L. Buchwald
Keyword(s):  
Aryl Halides ◽  
Halogen Exchange

The Metal—Halogen Exchange Reaction Between ortho-Substituted Aryl Halides and Ph2CuLi×LiCN: Scope and Applicability for Coupling Reactions.

ChemInform ◽  
2004 ◽  
Vol 35 (21) ◽  
Author(s):  
Fatma Cetin ◽  
H. Baris Senogul ◽  
Sibel Gezer ◽  
Demet Astley ◽  
Stephen T. Astley
Keyword(s):  
Exchange Reaction ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Halogen Exchange

The metal–halogen exchange reaction between ortho-substituted aryl halides and Ph2CuLi·LiCN: scope and applicability for coupling reactions

2004 ◽  
Vol 689 (1) ◽  
pp. 154-157 ◽  
Author(s):  
Fatma Çetin ◽  
H. Barış Şenoǧul ◽  
Sibel Gezer ◽  
Demet Astley ◽  
Stephen T. Astley
Keyword(s):  
Exchange Reaction ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Halogen Exchange

Mild Temperature Copper-Catalyzed Amination of Aryl Halides with Aqueous Ammonia in the Presence of Pyridyldiketone Ligands

2019 ◽  
Author(s):  
Racha Abed Ali Abdine ◽  
Anna Walczak ◽  
Sultan Abu A Aeash ◽  
Gracjan Kurpik ◽  
Artur R. Stefankiewicz ◽  
...  
Keyword(s):  
Catalytic System ◽  
Aqueous Ammonia ◽  
Aryl Halides ◽  
Efficient Coupling ◽  
Ambidentate Ligand ◽  
Mild Temperature

Ambidentate ligand pyridyldiketones were used in combination with copper to catalyze maintain of aryl halides under very mild temperatures. This novel catalytic system allow efficient coupling in one of the smoothest conditions ever reported in literature.

Carbon-Heteroatom Cross-Coupling via an Electronically Excited Nickel (II) Complex

2019 ◽  
Author(s):  
Randolph Escobar ◽  
Jeffrey Johannes
Keyword(s):  
Energy Transfer ◽  
Functional Groups ◽  
Cross Coupling ◽  
Reductive Elimination ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
General Methodology ◽  
Cross Coupling Reactions ◽  
Electronically Excited ◽  
Energy Transfer Pathway

<div>While carbon-heteroatom cross coupling reactions have been extensively studied, many methods are specific and</div><div>limited to a set of substrates or functional groups. Reported here is a method that allows for C-O, C-N and C-S cross coupling reactions under one general methodology. We propose that an energy transfer pathway, in which an iridium photosensitizer produces an excited nickel (II) complex, is responsible for the key reductive elimination step that couples aryl halides to 1° and 2° alcohols, anilines, thiophenols, carbamates and sulfonamides.</div>

Chiral Mn(III) Salen Complex Immobilized on CuFe2O4@SiO2-NH2 NPs: A Cheap and Efficient Catalyst for N-arylation of Aryl Halides and Phenylboronic Acid Under Mild Conditions

2020 ◽  
Vol 17 (11) ◽  
pp. 857-863
Author(s):  
Mohammad Ali Nasseri ◽  
Seyyedeh Ameneh Alavi ◽  
Milad Kazemnejadi ◽  
Ali Allahresani
Keyword(s):  
Phenylboronic Acid ◽  
Significant Loss ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Aryl Chlorides ◽  
Mild Conditions ◽  
Cross Coupling Reactions ◽  
Salen Complex ◽  
Ft Ir

A convenient and efficient chiral CuFe2O4@SiO2-Mn(III) Ch.salen nanocatalyst has been developed for the C-N cross-coupling reactions of aryl halides/ phenylboronic acid with N-heterocyclic compounds in water and/or DMSO under mild conditions. The catalyst could be applied for the N-arylation of a variety of nitrogen-containing heterocycles with aryl chlorides, bromides, iodides and phenylboronic acid under mild conditions. Moderate to good yields were achieved for all substrates. The structure of catalyst was characterized using various techniques including FT-IR, FE-SEM, EDX, XRD, TEM and TGA. The catalyst can be simply recovered and reused for several times without significant loss of activity.

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