Ruthenium-Catalyzed Propargylic Substitution Reaction of Propargylic Alcohols with Thiols:  A General Synthetic Route to Propargylic Sulfides

2002 ◽  
Vol 124 (51) ◽  
pp. 15172-15173 ◽  
Author(s):  
Youichi Inada ◽  
Yoshiaki Nishibayashi ◽  
Masanobu Hidai ◽  
Sakae Uemura
Keyword(s):  
Substitution Reaction ◽  
Synthetic Route ◽  
Propargylic Alcohols ◽  
Propargylic Substitution

BiCl3-Catalyzed propargylic substitution reaction of propargylic alcohols with C-, O-, S- and N-centered nucleophiles

2006 ◽  
pp. 3352 ◽  
Author(s):  
Zhuang-ping Zhan ◽  
Wen-zhen Yang ◽  
Rui-feng Yang ◽  
Jing-liang Yu ◽  
Jun-ping Li ◽  
...  
Keyword(s):  
Substitution Reaction ◽  
Propargylic Alcohols ◽  
Propargylic Substitution

BiCl3-Catalyzed Propargylic Substitution Reaction of Propargylic Alcohols with C-, O-, S- and N-Centered Nucleophiles.

ChemInform ◽  
2006 ◽  
Vol 37 (52) ◽  
Author(s):  
Zhuang-ping Zhan ◽  
Wen-zhen Yang ◽  
Rui-feng Yang ◽  
Jing-liang Yu ◽  
Jun-ping Li ◽  
...  
Keyword(s):  
Substitution Reaction ◽  
Propargylic Alcohols ◽  
Propargylic Substitution

Chlorido(dimethyl 2,2′-bipyridine-4,4′-dicarboxylate-κ2N,N′)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride 1-hydroxypyrrolidine-2,5-dione disolvate

2013 ◽  
Vol 69 (6) ◽  
pp. 584-587
Author(s):  
Dharmalingam Sivanesan ◽  
Hyung Min Kim ◽  
Yoon Sungho
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Substitution Reaction ◽  
Three Dimensional ◽  
Title Complex ◽  
Rhodium Complex ◽  
Synthetic Route ◽  
Dimensional Network ◽  
Weak Hydrogen Bonds ◽  
Solvent Molecules

The title complex, [Rh(C10H15)Cl(C14H12N2O4)]Cl·2C4H5NO3, has been synthesized by a substitution reaction of the precursor [bis(2,5-dioxopyrrolidin-1-yl) 2,2′-bipyridine-4,4′-dicarboxylate]chlorido(pentamethylcyclopentadienyl)rhodium(III) chloride with NaOCH3. The RhIIIcation is located in an RhC5N2Cl eight-coordinated environment. In the crystal, 1-hydroxypyrrolidine-2,5-dione (NHS) solvent molecules form strong hydrogen bonds with the Cl−counter-anions in the lattice and weak hydrogen bonds with the pentamethylcyclopentadienyl (Cp*) ligands. Hydrogen bonding between the Cp* ligands, the NHS solvent molecules and the Cl−counter-anions form links in a V-shaped chain of RhIIIcomplex cations along thecaxis. Weak hydrogen bonds between the dimethyl 2,2′-bipyridine-4,4′-dicarboxylate ligands and the Cl−counter-anions connect the components into a supramolecular three-dimensional network. The synthetic route to the dimethyl 2,2′-bipyridine-4,4′-dicarboxylate-containing rhodium complex from the [bis(2,5-dioxopyrrolidin-1-yl) 2,2′-bipyridine-4,4′-dicarboxylate]rhodium(III) precursor may be applied to link Rh catalysts to the surface of electrodes.

scholarly journals Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Alcohols with Acetone

2006 ◽  
Vol 118 (4) ◽  
pp. 547-547
Author(s):  
Youichi Inada ◽  
Yoshiaki Nishibayashi ◽  
Sakae Uemura
Keyword(s):  
Substitution Reactions ◽  
Propargylic Alcohols ◽  
Propargylic Substitution

Double Phosphinylation of Propargylic Alcohols:  A Novel Synthetic Route to 1,2-Bis(diphenylphosphino)ethane Derivatives†

2004 ◽  
Vol 6 (22) ◽  
pp. 3993-3995 ◽  
Author(s):  
Marilyn Daisy Milton ◽  
Gen Onodera ◽  
Yoshiaki Nishibayashi ◽  
Sakae Uemura
Keyword(s):  
Synthetic Route ◽  
Propargylic Alcohols

Propargylic Substitution Reaction Catalyzed by Group IV (Ti, Zr, Hf)–Ru Heterobimetallic Complexes

2011 ◽  
Vol 30 (11) ◽  
pp. 3194-3199 ◽  
Author(s):  
Takamasa Miyazaki ◽  
Yoshiaki Tanabe ◽  
Masahiro Yuki ◽  
Yoshihiro Miyake ◽  
Yoshiaki Nishibayashi
Keyword(s):  
Substitution Reaction ◽  
Group Iv ◽  
Heterobimetallic Complexes ◽  
Propargylic Substitution
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