Normal and Inverse Primary Kinetic Deuterium Isotope Effects for C−H Bond Reductive Elimination and Oxidative Addition Reactions of Molybdenocene and Tungstenocene Complexes:  Evidence for Benzene σ-Complex Intermediates

David G. Churchill; Kevin E. Janak; Joshua S. Wittenberg; Gerard Parkin

doi:10.1021/ja027670k

Normal and Inverse Primary Kinetic Deuterium Isotope Effects for C−H Bond Reductive Elimination and Oxidative Addition Reactions of Molybdenocene and Tungstenocene Complexes: Evidence for Benzene σ-Complex Intermediates

Journal of the American Chemical Society ◽

10.1021/ja027670k ◽

2003 ◽

Vol 125 (5) ◽

pp. 1403-1420 ◽

Cited By ~ 72

Author(s):

David G. Churchill ◽

Kevin E. Janak ◽

Joshua S. Wittenberg ◽

Gerard Parkin

Keyword(s):

Isotope Effects ◽

Oxidative Addition ◽

Reductive Elimination ◽

Addition Reactions ◽

Deuterium Isotope Effects

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Kinetic and Equilibrium Deuterium Isotope Effects for C—H Bond Reductive Elimination and Oxidative Addition Reactions Involving theAnsa—Tungstenocene Methyl—Hydride Complex [Me2Si(C5Me4)2]W(Me)H

ACS Symposium Series - Activation and Functionalization of C—H Bonds ◽

10.1021/bk-2004-0885.ch005 ◽

2004 ◽

pp. 86-104 ◽

Cited By ~ 2

Author(s):

Kevin E. Janak ◽

David G. Churchill ◽

Gerard Parkin

Keyword(s):

Isotope Effects ◽

Oxidative Addition ◽

Reductive Elimination ◽

Addition Reactions ◽

Hydride Complex ◽

Deuterium Isotope Effects

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Kinetic and Equilibrium Deuterium Isotope Effects for C?H Bond Reductive Elimination and Oxidative Addition Reactions Involving the ansa-Tungstenocene Methyl?Hydride Complex [Me2Si(C5Me4)2]W(Me)H

ChemInform ◽

10.1002/chin.200508252 ◽

2005 ◽

Vol 36 (8) ◽

Author(s):

Kevin E. Janak ◽

David G. Churchill ◽

Gerard Parkin

Keyword(s):

Isotope Effects ◽

Oxidative Addition ◽

Reductive Elimination ◽

Addition Reactions ◽

Hydride Complex ◽

Deuterium Isotope Effects

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Secondary .beta.-deuterium isotope effects on the rates and equilibria of organometallic oxidative addition/reductive elimination reactions

Journal of the American Chemical Society ◽

10.1021/ja00046a004 ◽

1992 ◽

Vol 114 (20) ◽

pp. 7629-7636 ◽

Cited By ~ 17

Author(s):

Michael J. Hostetler ◽

Robert G. Bergman

Keyword(s):

Isotope Effects ◽

Oxidative Addition ◽

Reductive Elimination ◽

Deuterium Isotope Effects ◽

Elimination Reactions

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Applications of deuterium isotope effects for probing aspects of reactions involving oxidative addition and reductive elimination of H–H and C–H bonds

Journal of Labelled Compounds and Radiopharmaceuticals ◽

10.1002/jlcr.1435 ◽

2007 ◽

Vol 50 (11-12) ◽

pp. 1088-1114 ◽

Cited By ~ 34

Author(s):

Gerard Parkin

Keyword(s):

Isotope Effects ◽

Oxidative Addition ◽

Reductive Elimination ◽

Deuterium Isotope Effects

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ChemInform Abstract: Applications of Deuterium Isotope Effects for Probing Aspects of Reactions Involving Oxidative Addition and Reductive Elimination of H-H and C-H Bonds

ChemInform ◽

10.1002/chin.200832251 ◽

2008 ◽

Vol 39 (32) ◽

Author(s):

Gerard Parkin

Keyword(s):

Isotope Effects ◽

Oxidative Addition ◽

Reductive Elimination ◽

Deuterium Isotope Effects

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Electrophilic (Li+) acceleration of C–H reductive elimination and oxidative addition reactions of Os(II)/Os(0) nitrosyl complexesElectronic supplementary information (ESI) available: full experimental and computational details. See http://www.rsc.org/suppdata/nj/b2/b200180m/

New Journal of Chemistry ◽

10.1039/b200180m ◽

2002 ◽

Vol 26 (5) ◽

pp. 498-502

Author(s):

Dmitry V. Yandulov ◽

Kenneth G. Caulton

Keyword(s):

Oxidative Addition ◽

Reductive Elimination ◽

Supplementary Information ◽

Addition Reactions

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Oxidative Addition Reactions of Organorhodium(I) Complexes Containing the Tridentate Ligand 2,6-Bis(diphenylphosphanylmethyl)pyridine [Rh(PNP)R] (R = CH3, C6H5) with Iodine and Methyl Iodide and Investigation of the Reductive Elimination

European Journal of Inorganic Chemistry ◽

10.1002/(sici)1099-0682(199903)1999:3<435::aid-ejic435>3.0.co;2-h ◽

1999 ◽

Vol 1999 (3) ◽

pp. 435-440 ◽

Cited By ~ 25

Author(s):

Christine Hahn ◽

Michael Spiegler ◽

Eberhardt Herdtweck ◽

Rudolf Taube

Keyword(s):

Methyl Iodide ◽

Oxidative Addition ◽

Reductive Elimination ◽

Tridentate Ligand ◽

Addition Reactions

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ChemInform Abstract: THEORY OF α-KETO ACIDS. XXII. SECONDARY THERMODYNAMIC AND KINETIC DEUTERIUM ISOTOPE EFFECTS IN NUCLEOPHILIC ADDITION REACTIONS OF THE α-CARBONYL GROUP OF PYRUVAMIDE

Chemischer Informationsdienst ◽

10.1002/chin.197646113 ◽

1976 ◽

Vol 7 (46) ◽

pp. no-no

Author(s):

G. FISCHER ◽

G. KUELLERTZ ◽

A. SCHELLENBERGER

Keyword(s):

Carbonyl Group ◽

Nucleophilic Addition ◽

Isotope Effects ◽

Addition Reactions ◽

Abstract Theory ◽

Keto Acids ◽

Deuterium Isotope Effects

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Model calculations of secondary .alpha.-deuterium isotope effects in addition reactions to olefinic double bonds

The Journal of Physical Chemistry ◽

10.1021/j100668a019 ◽

1972 ◽

Vol 76 (24) ◽

pp. 3613-3617 ◽

Cited By ~ 4

Author(s):

I. Safarik ◽

O. P. Strausz

Keyword(s):

Isotope Effects ◽

Addition Reactions ◽

Double Bonds ◽

Model Calculations ◽

Deuterium Isotope Effects

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ChemInform Abstract: Reductive Elimination Leading to Transient (η5-C5Me5)Ru(NO). Trapping, Dimerization, and Oxidative Addition Reactions of This Intermediate and the Effect of Structural Variation on Its Generation.

ChemInform ◽

10.1002/chin.198744302 ◽

1987 ◽

Vol 18 (44) ◽

Author(s):

J. CHANG ◽

R. G. BERGMAN

Keyword(s):

Structural Variation ◽

Oxidative Addition ◽

Reductive Elimination ◽

Addition Reactions

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