Electron and Hydrogen-Atom Self-Exchange Reactions of Iron and Cobalt Coordination Complexes

Jeffrey C. Yoder; Justine P. Roth; Emily M. Gussenhoven; Anna S. Larsen; James M. Mayer

doi:10.1021/ja0273905

Electron and Hydrogen-Atom Self-Exchange Reactions of Iron and Cobalt Coordination Complexes

Journal of the American Chemical Society ◽

10.1021/ja0273905 ◽

2003 ◽

Vol 125 (9) ◽

pp. 2629-2640 ◽

Cited By ~ 42

Author(s):

Jeffrey C. Yoder ◽

Justine P. Roth ◽

Emily M. Gussenhoven ◽

Anna S. Larsen ◽

James M. Mayer

Keyword(s):

Hydrogen Atom ◽

Coordination Complexes ◽

Exchange Reactions ◽

Cobalt Coordination

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Proton-Coupled Electron Transfer versus Hydrogen Atom Transfer in Benzyl/Toluene, Methoxyl/Methanol, and Phenoxyl/Phenol Self-Exchange Reactions

Journal of the American Chemical Society ◽

10.1021/ja012732c ◽

2002 ◽

Vol 124 (37) ◽

pp. 11142-11147 ◽

Cited By ~ 232

Author(s):

James M. Mayer ◽

David A. Hrovat ◽

Jennie L. Thomas ◽

Weston Thatcher Borden

Keyword(s):

Electron Transfer ◽

Hydrogen Atom ◽

Hydrogen Atom Transfer ◽

Atom Transfer ◽

Exchange Reactions ◽

Proton Coupled Electron Transfer

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KINETICS OF DECOMPOSITION OF COBALT COORDINATION COMPLEXES ON MONTMORILLONITE SURFACES

Clays and Clay Minerals ◽

10.1016/b978-0-08-011908-3.50016-5 ◽

1966 ◽

pp. 163-179 ◽

Cited By ~ 2

Author(s):

J.J. FRIPIAT ◽

J. HELSEN

Keyword(s):

Coordination Complexes ◽

Kinetics Of Decomposition ◽

Cobalt Coordination ◽

Kinetics Of

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A combined experimental, theoretical, and Van't Hoff model study for identity methyl, proton, hydrogen atom, and hydride exchange reactions. Correlation with three-center four-, three-, and two-electron systems

International Journal of Quantum Chemistry ◽

10.1002/qua.21683 ◽

2008 ◽

Vol 108 (9) ◽

pp. 1601-1614 ◽

Cited By ~ 9

Author(s):

Henk M. Buck

Keyword(s):

Hydrogen Atom ◽

Electron Systems ◽

Exchange Reactions ◽

Methyl Proton ◽

Model Study

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Harnessing the properties of cobalt coordination complexes for biological application

Coordination Chemistry Reviews ◽

10.1016/j.ccr.2017.11.027 ◽

2018 ◽

Vol 375 ◽

pp. 221-233 ◽

Cited By ~ 30

Author(s):

Anna K. Renfrew ◽

Edward S. O'Neill ◽

Trevor W. Hambley ◽

Elizabeth J. New

Keyword(s):

Coordination Complexes ◽

Biological Application ◽

Cobalt Coordination

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Reduced-Dimensionality Semiclassical Transition State Theory: Application to Hydrogen Atom Abstraction and Exchange Reactions of Hydrocarbons

The Journal of Physical Chemistry A ◽

10.1021/acs.jpca.5b04379 ◽

2015 ◽

Vol 119 (50) ◽

pp. 12015-12027 ◽

Cited By ~ 19

Author(s):

Samuel M. Greene ◽

Xiao Shan ◽

David C. Clary

Keyword(s):

Hydrogen Atom ◽

Transition State ◽

Transition State Theory ◽

State Theory ◽

Hydrogen Atom Abstraction ◽

Exchange Reactions ◽

Reduced Dimensionality ◽

Theory Application

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The Third Dimension of a More O’Ferrall–Jencks Diagram for Hydrogen Atom Transfer in the Isoelectronic Hydrogen Exchange Reactions of (PhX)2H• with X = O, NH, and CH2

Journal of Chemical Theory and Computation ◽

10.1021/ct3004595 ◽

2012 ◽

Vol 8 (11) ◽

pp. 4347-4358 ◽

Cited By ~ 19

Author(s):

Alessandro Cembran ◽

Makenzie R. Provorse ◽

Changwei Wang ◽

Wei Wu ◽

Jiali Gao

Keyword(s):

Hydrogen Atom ◽

Hydrogen Exchange ◽

Hydrogen Atom Transfer ◽

Atom Transfer ◽

Exchange Reactions ◽

The Third ◽

Third Dimension

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Probing the Structural, Bonding, and Magnetic Properties of Cobalt Coordination Complexes: Co–Benzene, Co–Pyridine, and Co–Pyrimidine

The Journal of Physical Chemistry A ◽

10.1021/jp408971a ◽

2013 ◽

Vol 117 (48) ◽

pp. 12998-13008 ◽

Cited By ~ 5

Author(s):

Peng Shao ◽

Xiao-Yu Kuang ◽

Li-Ping Ding

Keyword(s):

Magnetic Properties ◽

Coordination Complexes ◽

Structural Bonding ◽

Cobalt Coordination

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Kinetics of Decomposition of Cobalt Coordination Complexes on Montmorillonite Surfaces

Clays and Clay Minerals ◽

10.1346/ccmn.1966.0140114 ◽

1966 ◽

Vol 14 (1) ◽

pp. 163-179 ◽

Cited By ~ 16

Author(s):

J. J. Fripiat

Keyword(s):

Coordination Complexes ◽

Kinetics Of Decomposition ◽

Cobalt Coordination ◽

Kinetics Of

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Lanthanum, Gallium and their Impact on Oxidative Stress

Current Medicinal Chemistry ◽

10.2174/0929867326666190104165311 ◽

2019 ◽

Vol 26 (22) ◽

pp. 4280-4295 ◽

Cited By ~ 2

Author(s):

Lozan Todorov ◽

Irena Kostova ◽

Maria Traykova

Keyword(s):

Oxidative Stress ◽

Anticancer Agents ◽

Human Exposure ◽

Coordination Complexes ◽

Modern Technology ◽

Present Review ◽

High Tech ◽

Exchange Reactions ◽

Living Organisms ◽

The Impact

The role metals play in living organisms is well established and subject to extensive research. Some of them participate in electron-exchange reactions. Such reactions cause generation of free radicals that can adversely impact biological systems, as a result of oxidative stress. The impact of ‘non-biological’ metals on oxidative stress is also a worthy pursuit due to the crucial role they play in modern civilization. Lanthanides (Ln) are widely used in modern technology. As a result, human exposure to them is increasing. They have a number of established medical applications and are being extensively researched for their potential antiviral, anticancer and anti-inflammatory properties. The present review focuses on lanthanum (La) and its impact on oxidative stress. Another metal, widely used in modern high-tech is gallium (Ga). In some respects, it shows certain similarities to La, therefore it is a subject of the present review as well. Both metals exhibit ionic mimicry which allows them to specifically target malignant cells, initiating apoptosis that makes their simple salts and coordination complexes promising candidates for future anticancer agents.

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