Factors Affecting the Rates of Addition of Free Radicals to AlkenesDetermination of Absolute Rate Coefficients Using the Persistent Aminoxyl Method

2002 ◽  
Vol 124 (32) ◽  
pp. 9489-9497 ◽  
Author(s):  
Athelstan L. J. Beckwith ◽  
James S. Poole
Keyword(s):  
Free Radicals ◽  
Rate Coefficients ◽  
Absolute Rate ◽  
Factors Affecting

scholarly journals Thiyl and phenoxyl free radicals and NADH Direct observation of one-electron oxidation

1986 ◽  
Vol 240 (3) ◽  
pp. 897-903 ◽  
Author(s):  
L G Forni ◽  
R L Willson
Keyword(s):  
Electron Transfer ◽  
Free Radicals ◽  
Hydrogen Atom ◽  
Pulse Radiolysis ◽  
Biological Significance ◽  
Transfer Reactions ◽  
Absolute Rate ◽  
Transfer Processes ◽  
Biochemical Systems ◽  
Electron Transfer Processes

Absolute rate constants for the reaction of NADH with thiyl free radicals derived from various sulphur-containing compounds of biological significance were measured by using the technique of pulse radiolysis. These and related reactions with phenoxyl free radicals are believed to occur through one-electron-transfer processes. Further evidence comes from studies with deuterated NADH. The results support the possibility that, in biochemical systems, thiols may act as catalysts linking hydrogen-atom and electron-transfer reactions.

Factors affecting stability and equilibria of free radicals—IX

Tetrahedron ◽  
1977 ◽  
Vol 33 (17) ◽  
pp. 2249-2253 ◽  
Author(s):  
A.T. Balaban ◽  
M.T. Cǎproiu ◽  
N. Negoiţǎ ◽  
R. Baican
Keyword(s):  
Free Radicals ◽  
Factors Affecting

Factors affecting stability and equilibria of free radicals—VIII

Tetrahedron ◽  
1974 ◽  
Vol 30 (1) ◽  
pp. 73-74 ◽  
Author(s):  
N. Negoiţǎ ◽  
R. Baican ◽  
A.T. Balaban
Keyword(s):  
Free Radicals ◽  
Factors Affecting

Absolute rate coefficients over extended temperature ranges and mechanisms of the CF(X2Π) reactions with F2, Cl2 and O2

2009 ◽  
Vol 11 (21) ◽  
pp. 4319 ◽  
Author(s):  
B. Vetters ◽  
B. Dils ◽  
T. L. Nguyen ◽  
L. Vereecken ◽  
S. A. Carl ◽  
...  
Keyword(s):  
Rate Coefficients ◽  
Absolute Rate ◽  
Temperature Ranges

Factors affecting stability and equilibria of free radicals

Tetrahedron ◽  
1961 ◽  
Vol 13 (4) ◽  
pp. 258-267 ◽  
Author(s):  
A.T. Balaban ◽  
P.T. Frangopol ◽  
M. Marculescu ◽  
J. Bally
Keyword(s):  
Free Radicals ◽  
Factors Affecting
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