Measurements of Electron-Transfer Rates of Charge-Storage Molecular Monolayers on Si(100). Toward Hybrid Molecular/Semiconductor Information Storage Devices

2003 ◽  
Vol 125 (2) ◽  
pp. 505-517 ◽  
Author(s):  
Kristian M. Roth ◽  
Amir A. Yasseri ◽  
Zhiming Liu ◽  
Rajeev B. Dabke ◽  
Vladimir Malinovskii ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Information Storage ◽  
Charge Storage ◽  
Transfer Rates ◽  
Storage Devices ◽  
Molecular Monolayers ◽  
Molecular Semiconductor

scholarly journals Recent Advances in Biomolecule–Nanomaterial Heterolayer-Based Charge Storage Devices for Bioelectronic Applications

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3520
Author(s):  
Taek Lee ◽  
Soomin Kim ◽  
Jinmyeong Kim ◽  
Sang-Chan Park ◽  
Jinho Yoon ◽  
...  
Keyword(s):  
Industrial Revolution ◽  
Field Effect Transistors ◽  
Information And Communications Technology ◽  
Information Storage ◽  
Charge Storage ◽  
Communications Technology ◽  
Promising Alternative ◽  
Storage Devices ◽  
Fourth Industrial Revolution ◽  
Recent Advances

With the acceleration of the Fourth Industrial Revolution, the development of information and communications technology requires innovative information storage devices and processing devices with low power and ultrahigh stability. Accordingly, bioelectronic devices have gained considerable attention as a promising alternative to silicon-based devices because of their various applications, including human-body-attached devices, biomaterial-based computation systems, and biomaterial–nanomaterial hybrid-based charge storage devices. Nanomaterial-based charge storage devices have witnessed considerable development owing to their similarity to conventional charge storage devices and their ease of applicability. The introduction of a biomaterial-to-nanomaterial-based system using a combination of biomolecules and nanostructures provides outstanding electrochemical, electrical, and optical properties that can be applied to the fabrication of charge storage devices. Here, we describe the recent advances in charge storage devices containing a biomolecule and nanoparticle heterolayer including (1) electrical resistive charge storage devices, (2) electrochemical biomemory devices, (3) field-effect transistors, and (4) biomemristors. Progress in biomolecule–nanomaterial heterolayer-based charge storage devices will lead to unprecedented opportunities for the integration of information and communications technology, biotechnology, and nanotechnology for the Fourth Industrial Revolution.

A Bipodal-Tethered Porphyrin for Attachment to Silicon Surfaces in Studies of Molecular Information Storage

2008 ◽  
Vol 8 (9) ◽  
pp. 4813-4817 ◽  
Author(s):  
Izabela Schmidt ◽  
Jieying Jiao ◽  
David F. Bocian ◽  
Jonathan S. Lindsey
Keyword(s):  
Structural Features ◽  
Information Storage ◽  
Silicon Surfaces ◽  
Transfer Rates ◽  
Zinc Porphyrin ◽  
Molecular Monolayers ◽  
Redox Active ◽  
High Charge Density ◽  
Electrochemical Cycling ◽  
Molecular Information

An approach for molecular information storage entails use of redox-active molecules attached to an electroactive surface. Understanding the structural features that give rise to robust molecular monolayers with high charge density is an essential objective. Toward this goal, a zinc-porphyrin bearing an all-carbon bipodal tether, 5-(1,6-heptadien-4-yl)-15-phenyl-10,20-di-p-tolylporphinatozinc(II), has been synthesized by the reaction of a dipyrromethane and a dipyrromethane-1,9-dicarbinol. The porphyrin was attached to Si(100) via a high temperature procedure. The resulting molecular monolayers exhibited surface coverages, adsorption geometries, electron-transfer rates, and stabilities under repeated electrochemical cycling that are similar to those obtained with monopodal carbon tethers. The observation that the bipodal anchor does not provide enhanced stability is surprising given that attachment is achieved via two versus one covalent linkage.

Photo-induced variation of magnetism in coordination polymers with ligand-based electron transfer

2021 ◽  
Author(s):  
Yan-Lei Lu ◽  
Wen-Long Lan ◽  
Wei Shi ◽  
Qionghua Jin ◽  
Peng Cheng
Keyword(s):  
Electron Transfer ◽  
Coordination Polymers ◽  
Optical Memory ◽  
High Density ◽  
Information Storage ◽  
Memory Devices ◽  
Storage Materials ◽  
Potential Applications ◽  
Induced Variation

Photo-induced variation of magnetism from ligand-based electron transfer have been extensively studied because of their potential applications in magneto-optical memory devices, light-responsive switches, and high-density information storage materials. In this...

Quantification of Electron Transfer Rates to a Solid Phase Electron Acceptor through the Stages of Biofilm Formation from Single Cells to Multicellular Communities

2010 ◽  
Vol 44 (7) ◽  
pp. 2721-2727 ◽  
Author(s):  
Jeffrey S. McLean ◽  
Greg Wanger ◽  
Yuri A. Gorby ◽  
Martin Wainstein ◽  
Jeff McQuaid ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electron Acceptor ◽  
Biofilm Formation ◽  
Solid Phase ◽  
Single Cells ◽  
Transfer Rates

scholarly journals Ionic Liquids in Charge Storage Devices: Effect of Purification on Performance

10.5772/23870 ◽  
2011 ◽  
Author(s):  
John D. ◽  
Andrew P. ◽  
Clare F. Kline Jr. ◽  
Gregory S. ◽  
Roxanne L.
Keyword(s):  
Ionic Liquids ◽  
Charge Storage ◽  
Storage Devices

Four Aspects of the Distance Dependence of Electron-Transfer Rates

1982 ◽  
pp. 213-233 ◽  
Author(s):  
EPHRAIM BUHKS ◽  
RALPH G. WILKINS ◽  
STEPHAN S. ISIED ◽  
JOHN F. ENDICOTT
Keyword(s):  
Electron Transfer ◽  
Transfer Rates ◽  
Distance Dependence

Electron Transfer Rates in Mitochondrial Proteins: Regulation and Specificity

1989 ◽  
pp. 131-140 ◽  
Author(s):  
G. McLendon ◽  
Q. Zhang ◽  
K. Pardue ◽  
F. Sherman ◽  
A. Corin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Mitochondrial Proteins ◽  
Transfer Rates
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