scholarly journals THE ADIABATIC DETERMINATION OF HEATS OF SOLUTION OF METALS IN ACIDS. PART II. THE HEAT OF DILUTION OF THE ACID SOLUTIONS.

1910 ◽  
Vol 32 (10) ◽  
pp. 1176-1186 ◽  
Author(s):  
Theodore W. Richards ◽  
Allen W. Rowe ◽  
L. L. Burgess
Keyword(s):  
Acid Solutions ◽  
Heat Of Dilution ◽  
Heats Of Solution

Zur Thermodynamik der hydrophoben Wechselwirkung; die Systeme Wasser + Glycin+ Harnstoff und Wasser + Alanin+ Harnstoff bei 25 °C / Thermodynamics of Hydrophobie Interaction in the Systems Water + Glycin + Urea and Water + Alanin + Urea at 25 °C

1973 ◽  
Vol 28 (9-10) ◽  
pp. 533-554 ◽  
Author(s):  
Lothar Rafflenbeul ◽  
Wa-Ming Pang ◽  
Hansjürgen Schönert ◽  
Klaus Haberle
Keyword(s):  
Amino Acid ◽  
Magnetic Resonance ◽  
Proton Magnetic Resonance ◽  
Pressure Measurements ◽  
Free Enthalpy ◽  
Heat Of Dilution ◽  
Ternary Solutions ◽  
Vapor Pressure Measurements ◽  
Calorimetric Determination

Abstract Isopiestic vapor pressure measurements and calorimetric determination of the heat of dilution have been performed and evaluated with respect to enthalpy, entropy and free enthalpy in the ternary solutions water+ glycin+ urea and water+ alanin + urea. The free enthalpy of transfer for the process: Amino acid from water to water+ urea, which can be derived from these measurements, does not agree with the value calculated from solubility measurements. The reason for this discrepancy and the values of entropy and enthalpy in terms of hydrophobic interaction are discussed. Supplementary measurements of the proton magnetic resonance in these solutions are included.

scholarly journals THE ADIABATIC DETERMINATION OF THE HEATS OF SOLUTION OF METALS IN ACIDS.

1910 ◽  
Vol 32 (4) ◽  
pp. 431-460 ◽  
Author(s):  
Theodore William Richards ◽  
Laurie Lorne Burgess
Keyword(s):  
Heats Of Solution

Simultaneous radiometric determination of uranium and thorium in sulfuric acid solutions

1972 ◽  
Vol 31 (6) ◽  
pp. 1425-1427 ◽  
Author(s):  
V. V. Anosov ◽  
N. I. Gavrilov ◽  
T. P. Smelkova
Keyword(s):  
Sulfuric Acid ◽  
Acid Solutions ◽  
Sulfuric Acid Solutions ◽  
Radiometric Determination

Determination of Aluminum in Chromic-Phosphoric Acid Solutions

1956 ◽  
Vol 28 (10) ◽  
pp. 1571-1576 ◽  
Author(s):  
Cornelius. Groot ◽  
R. M. Peekema ◽  
V. H. Troutner
Keyword(s):  
Phosphoric Acid ◽  
Acid Solutions

A simple procedure using trinitrobenzenesulphonic acid for monitoring proteolysis in cheese

1988 ◽  
Vol 55 (4) ◽  
pp. 585-596 ◽  
Author(s):  
Anna Polychroniadou
Keyword(s):  
Simple Procedure ◽  
Water Soluble ◽  
Acid Solutions ◽  
Amino Groups ◽  
Total N ◽  
Cheese Ripening ◽  
Amino Acid Solutions ◽  
Hydrolysis Of ◽  
Good Agreement

SummaryA simple, rapid and sensitive spectrophotometric assay was developed and evaluated for monitoring proteolysis during cheese ripening, based on the fact that α-amino groups released by hydrolysis of cheese proteins react with trinitrobenzenesulphonic acid to form products that absorb strongly at 420 nm. A linear relationship was shown to exist between A420 and concentration of free α amino groups up to 0·5 HIM (r = 0·999, 38 df, P < 0·001). Repeatability of the method was satisfactory. The coefficient of variance was 0·53% for amino acid solutions and 1·19% for cheese extracts. Average recovery of glycine added to the cheese was 104 ± 2·9%. A comparison of the above method with that of determination of water-soluble N to total N ratio showed that there was good agreement between these two methods of assessment of proteolysis in cheese (r = 0·857, 32 df, P < 0·001). Mainly Feta and Teleme cheese were examined, but a similar correlation was obtained with hard Greek cheeses. Analytical conditions of the procedure are discussed.

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