A Note on the Phase Rule Diagram for a Mixture of Sodium Palmitate and Sodium Laurate with Water

1941 ◽  
Vol 63 (3) ◽  
pp. 875-875
Author(s):  
J. W. McBain ◽  
S. A. Johnston
2010 ◽  
Vol 7 (4) ◽  
pp. 1491-1497 ◽  
Author(s):  
Millicent U. Ibezim-Ezeani ◽  
Alphonso C. I. Anusiem

The effect of ionic charge on the adsorption of sodium-palmitate and sodium-laurate onto galena, hematite and cassiterite surfaces in aqueous media was studied. The adsorption capacities were determined as a function of adsorbate concentration in the presence of various anions and cations at pH 7.31 and 29 °C. Positively charged ions depressed the adsorption capacity in the order: K+> Ba2+> Al3+, showing a reverse correlation with the charge to size ratio of these ions indicating a possible expansion of the double layer that results from predominant diffusion effect and electrostatic effect to some extent. The negatively charged ion enhanced adsorption capacity in the order: PO43-> SO42-> NO3-. This is attributed to the compression of the double layer through electrostatic interaction. In all the studies the adsorption capacities for the adsorbents were in the order: galena > hematite > cassiterite corresponding to the trend in the specific surface area of the adsorbents.


1943 ◽  
Vol 47 (7) ◽  
pp. 528-535 ◽  
Author(s):  
O. E. A. Bolduan ◽  
J. W. McBain ◽  
Sydney Ross

1938 ◽  
Vol 60 (8) ◽  
pp. 1870-1876 ◽  
Author(s):  
J. W. McBain ◽  
G. C. Brock ◽  
R. D. Vold ◽  
M. J. Vold

1939 ◽  
Vol 61 (9) ◽  
pp. 2540-2544
Author(s):  
J. W. McBain ◽  
Josephine M. McDowell ◽  
Margaret E. Worden

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