scholarly journals Selective Pd-Catalyzed Oxidative Coupling of Anilides with Olefins through C−H Bond Activation at Room Temperature

2002 ◽  
Vol 124 (8) ◽  
pp. 1586-1587 ◽  
Author(s):  
Maarten D. K. Boele ◽  
Gino P. F. van Strijdonck ◽  
André H. M. de Vries ◽  
Paul C. J. Kamer ◽  
Johannes G. de Vries ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Room Temperature ◽  
Bond Activation

ChemInform Abstract: Selective Pd-Catalyzed Oxidative Coupling of Anilides with Olefins Through C-H Bond Activation at Room Temperature.

ChemInform ◽  
2010 ◽  
Vol 33 (28) ◽  
pp. no-no
Author(s):  
Maarten D. K. Boele ◽  
Gino P. F. van Strijdonck ◽  
Andre H. M. de Vries ◽  
Paul C. J. Kamer ◽  
Johannes G. de Vries ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Room Temperature ◽  
Bond Activation

Room temperature selective oxidation of aniline to azoxybenzene over a silver supported tungsten oxide nanostructured catalyst

2015 ◽  
Vol 17 (3) ◽  
pp. 1867-1876 ◽  
Author(s):  
Shilpi Ghosh ◽  
Shankha S. Acharyya ◽  
Takehiko Sasaki ◽  
Rajaram Bal
Keyword(s):  
Silver Nanoparticles ◽  
Tungsten Oxide ◽  
Selective Oxidation ◽  
Oxidative Coupling ◽  
Room Temperature ◽  
Heterogeneous Catalysts ◽  
Nanostructured Catalyst ◽  
Important Chemical

Heterogeneous catalysts comprising silver nanoparticles supported on nanostructured tungsten oxide were applied for room temperature oxidative coupling of aniline to azoxybenzene, an important chemical intermediate and a chemical of industrial interest.

Room-Temperature Selective Aliphatic Carbon–Carbon Bond Activation and Functionalization of Ethers by Rhodium(II) Porphyrin

2011 ◽  
Vol 30 (14) ◽  
pp. 3691-3693 ◽  
Author(s):  
Siu Yin Lee ◽  
Tsz Ho Lai ◽  
Kwong Shing Choi ◽  
Kin Shing Chan
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Aliphatic Carbon

CuWO4 as a photocatalyst for room temperature aerobic benzylamine oxidation

2018 ◽  
Vol 54 (9) ◽  
pp. 1101-1104 ◽  
Author(s):  
Aaron D. Proctor ◽  
Shobhana Panuganti ◽  
Bart M. Bartlett
Keyword(s):  
Oxidative Coupling ◽  
Oxidation Reaction ◽  
Room Temperature ◽  
Photo Oxidation

We report the first example of a controlled photo-oxidation reaction on CuWO4, the aerobic oxidative coupling of benzylamine.

The oxidative coupling between benzaldehyde derivatives and phenylacetylene catalyzed by rhodium complexes via C-H bond activation

2020 ◽  
Vol 26 (1) ◽  
pp. 20-25
Author(s):  
Xinyi Zhao ◽  
Hongge Jia ◽  
Qingji Wang ◽  
Heming Song ◽  
Yanan Tang ◽  
...  
Keyword(s):  
Amino Acid ◽  
Oxidative Coupling ◽  
Bond Activation ◽  
Coupling Reaction ◽  
Reaction Yield ◽  
Rhodium Complexes ◽  
Electronic Effects ◽  
Oxidative Coupling Reaction ◽  
Excellent Activity ◽  
Benzaldehyde Derivatives

AbstractThis paper reports the use of rhodium (Rh) catalysts for the oxidative coupling reaction between phenylacetylene and benzaldehyde derivatives via C-H bond activation. These reactions were catalyzed by Rh(l-amino acid)(cod) (the l-amino acid is l-phenylalanine, l-valine or l-proline; cod is 1,5-cyclooctadiene) to obtain chromones in 12.7–88.3% yield. These new Rh catalysts have excellent activity for the coupling reaction between phenylacetylene and different benzaldehyde derivatives. It was found that the electronic effects of the benzaldehyde derivative substituent affected the reaction yield, which is in accordance with the proposed mechanism.

scholarly journals Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

2016 ◽  
Vol 52 (88) ◽  
pp. 12960-12963 ◽  
Author(s):  
Andrea Monas ◽  
Krunoslav Užarević ◽  
Ivan Halasz ◽  
Marina Juribašić Kulcsár ◽  
Manda Ćurić
Keyword(s):  
Methyl Orange ◽  
Solid State ◽  
Room Temperature ◽  
Bond Activation ◽  
Aqueous Media ◽  
Accelerated Aging ◽  
Water Soluble ◽  
Clean Synthesis

Room-temperature accelerated aging in the solid state has been applied for quantitative azobenzene C–H bond activation by Pd(OAc)2. Water-soluble dicyclopalladated methyl orange is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in aqueous media.

scholarly journals Synthesis of Asthma Drug Zafirlukast (Accolate) Using Intramolecular Oxidative Coupling via sp3 C–H Bond Activation

ACS Omega ◽  
2018 ◽  
Vol 3 (4) ◽  
pp. 4289-4294 ◽  
Author(s):  
Srinu Paladugu ◽  
Prathama S. Mainkar ◽  
Srivari Chandrasekhar
Keyword(s):  
Oxidative Coupling ◽  
Bond Activation ◽  
Asthma Drug

scholarly journals Si–C(sp3) bond activation through oxidative addition at a Rh(i) centre

2020 ◽  
Vol 49 (17) ◽  
pp. 5416-5419
Author(s):  
S. Azpeitia ◽  
A. J. Martínez-Martínez ◽  
M. A. Garralda ◽  
A. S. Weller ◽  
M. A. Huertos
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Oxidative Addition

Rhodium promoted a fast, quantitative and room temperature Si–CH3 bond activation.

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