Free Radical Aromatic Substitution. III. The Relative Reactivities of Benzene, Benzonitrile and Methyl Benzenesulfonate toward Phenyl Radical Attack1,2

1954 ◽  
Vol 76 (11) ◽  
pp. 2997-3000 ◽  
Author(s):  
Ralph L. Dannley ◽  
Earl C. Gregg
Keyword(s):  
Free Radical ◽  
Phenyl Radical ◽  
Aromatic Substitution ◽  
Radical Aromatic Substitution

Metal-free radical aromatic carbonylations mediated by weak bases

2017 ◽  
Vol 15 (32) ◽  
pp. 6715-6719 ◽  
Author(s):  
Denis Koziakov ◽  
Axel Jacobi von Wangelin
Keyword(s):  
Free Radical ◽  
Aromatic Substitution ◽  
Metal Free ◽  
Weak Bases ◽  
Substitution Mechanism ◽  
Radical Aromatic Substitution

A radical aromatic substitution mechanism initiated by very weak bases affects the synthesis of benzoates under pressurized CO atmosphere.

scholarly journals Metal-free radical thiolations mediated by very weak bases

2016 ◽  
Vol 14 (48) ◽  
pp. 11347-11352 ◽  
Author(s):  
Denis Koziakov ◽  
Michal Majek ◽  
Axel Jacobi von Wangelin
Keyword(s):  
Free Radical ◽  
Aromatic Substitution ◽  
Metal Free ◽  
Weak Bases ◽  
Substitution Mechanism ◽  
Radical Aromatic Substitution

A radical aromatic substitution mechanism initiated by very weak bases effects the synthesis of thioethers and heavier chalcogenides.

Mechanisms of free-radical aromatic substitution

1962 ◽  
Vol 3 (17) ◽  
pp. 749-753 ◽  
Author(s):  
E.L. Eliel ◽  
M. Eberhardt ◽  
O. Simamura ◽  
S. Meyerson
Keyword(s):  
Free Radical ◽  
Aromatic Substitution ◽  
Radical Aromatic Substitution
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