The Diffusion Coefficients of Lithium and Potassium Perchlorates in Dilute Aqueous Solutions at 25°

1955 ◽  
Vol 77 (8) ◽  
pp. 2071-2073 ◽  
Author(s):  
Herbert S. Harned ◽  
Herman W. Parker ◽  
Milton Blander
Keyword(s):  
Aqueous Solutions ◽  
Diffusion Coefficients ◽  
Dilute Aqueous Solutions

The reactions of oligoalcohols with arsenic, arsenous, boric and germanic acids

1980 ◽  
Vol 45 (10) ◽  
pp. 2645-2655 ◽  
Author(s):  
Antonín Mikan ◽  
Miloš Bartušek
Keyword(s):  
Aqueous Solutions ◽  
Equilibrium Constants ◽  
Dilute Aqueous Solutions

The reactions of sorbitol, mannitol, adonitol, dulcitol, glucose and glycerol with H3AsO4, H3AsO3, H3BO3 and GeO2 acids in dilute aqueous solutions were studied by potentiometric neutralization titrations. The formation of the following chelates was demonstrated: As(V)L3-, As(III)L(OH)2-, HAs(III)L(OH)2, BL2-, GeL2(OH)- and GeL32- and the equilibrium constants for their formation were found. Conditions for formation of these chelates of organic oligohydroxy compounds are discussed.

Study of potential oscillations during reaction of an aluminium single crystal with an aqueous KOH solution

1990 ◽  
Vol 55 (2) ◽  
pp. 345-353 ◽  
Author(s):  
Ivan Halaša ◽  
Milica Miadoková
Keyword(s):  
Aqueous Solutions ◽  
Single Crystal ◽  
Single Crystals ◽  
Periodic Potential ◽  
Optimum Conditions ◽  
Potential Oscillations ◽  
Dilute Aqueous Solutions ◽  
Experimental Findings ◽  
Kinetics Of

The authors investigated periodic potential changes measured on oriented sections of Al single crystals during spontaneous dissolution in dilute aqueous solutions of KOH, with the aim to find optimum conditions for the formation of potential oscillations. It was found that this phenomenon is related with the kinetics of the reaction investigated, whose rate also changed periodically. The mechanism of the oscillations is discussed in view of the experimental findings.

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