Kinetics of Displacement Reactions at the Sulfur Atom. I. Isotopic Exchange between Sulfite and Alkylthiosulfates

1956 ◽  
Vol 78 (20) ◽  
pp. 5203-5208 ◽  
Author(s):  
Antonino Fava ◽  
Gastone Pajaro
Keyword(s):  
Sulfur Atom ◽  
Isotopic Exchange ◽  
Displacement Reactions ◽  
Kinetics Of

scholarly journals Kinetics of Isotopic Exchange between 8-Quinolinol-14C and Tris-8-quinolinolato Complexes of Tervalent Typical Elements

1968 ◽  
Vol 41 (5) ◽  
pp. 1139-1142 ◽  
Author(s):  
Kazuo Saito ◽  
Michihiko Takahashi ◽  
Yukio Miyakawa ◽  
Kazuyo Masuda
Keyword(s):  
Isotopic Exchange ◽  
Kinetics Of

THE KINETICS OF HETEROGENEOUS ISOTOPIC EXCHANGE

1972 ◽  
Vol 23 (1) ◽  
pp. 76-81 ◽  
Author(s):  
M. E. PROBERT ◽  
S. LARSEN
Keyword(s):  
Isotopic Exchange ◽  
Kinetics Of

Substituent Effect on Reactivity of Alkyl Thiolacetates

1971 ◽  
Vol 26 (7) ◽  
pp. 703-707
Author(s):  
F. Dutka ◽  
A. F. Márton ◽  
P. Vinkler
Keyword(s):  
Chemical Reaction ◽  
Sulfur Atom ◽  
Substituent Effect ◽  
Linear Structure ◽  
Common Mechanism ◽  
Reaction Site ◽  
Structure Reactivity Relationship ◽  
Kinetics Of

Kinetics of catalyzed acyl group exchange between acetic-1-14C anhydride and alkyl thiolacetates was investigated. The exchange is not accompanied by chemical reaction and demonstrates the full equivalency of anhydride acyl groups in the process. The rate of exchange is lowered by increasing branching rather than lengthening in S-alkyl substituents. The role of catalyst and structures of possible intermediates are interpreted. Upon existing linear structure-reactivity relationship a common mechanism involving sulfur atom as the reaction site seems to be operative.

Elovich Equation for the Kinetics of Isotopic Exchange Reactions at Solid–Liquid Interfaces

Nature ◽  
1970 ◽  
Vol 226 (5241) ◽  
pp. 148-149 ◽  
Author(s):  
R. J. ATKINSON ◽  
F. J. HINGSTON ◽  
A. M. POSNER ◽  
J. P. QUIRK
Keyword(s):  
Isotopic Exchange ◽  
Liquid Interfaces ◽  
Exchange Reactions ◽  
Elovich Equation ◽  
Solid Liquid ◽  
Kinetics Of
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