Medium Effects in the Homogeneous Catalytic Activation of Molecular Hydrogen by Metal Salts. III. Silver and Mercuric Salts1

1959 ◽  
Vol 81 (22) ◽  
pp. 5854-5857 ◽  
Author(s):  
A. J. Chalk ◽  
J. Halpern ◽  
A. C. Harkness
Keyword(s):  
Molecular Hydrogen ◽  
Metal Salts ◽  
Medium Effects ◽  
Catalytic Activation

CATALYTIC ACTIVATION OF HYDROGEN IN AQUEOUS SOLUTION BY THE CHLOROPALLADATE(II) ION

1959 ◽  
Vol 37 (9) ◽  
pp. 1446-1450 ◽  
Author(s):  
J. Halpern ◽  
J. F. Harrod ◽  
P. E. Potter
Keyword(s):  
Aqueous Solution ◽  
Ferric Chloride ◽  
Molecular Hydrogen ◽  
Homogeneous Catalyst ◽  
Rate Law ◽  
Catalytic Activation ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of the reduction of ferric chloride by molecular hydrogen in aqueous solution, in the presence of chloropalladate(II), were examined. The latter acts as a homogeneous catalyst for the reaction. The rate-law was found to be,[Formula: see text]where[Formula: see text]The mechanism of the reaction is discussed.

CATALYTIC ACTIVATION OF MOLECULAR HYDROGEN IN SOLUTION BY CHLORORHODATE(III) COMPLEXES

1959 ◽  
Vol 37 (11) ◽  
pp. 1933-1935 ◽  
Author(s):  
J. F. Harrod ◽  
J. Halpern
Keyword(s):  
Molecular Hydrogen ◽  
Catalytic Activation

not available

Catalytic Activation of Molecular Hydrogen by Aluminum Chloride

1957 ◽  
Vol 49 (6) ◽  
pp. 1054-1055 ◽  
Author(s):  
L. W. Wright ◽  
S. W. Weller ◽  
G. A. Mills
Keyword(s):  
Aluminum Chloride ◽  
Molecular Hydrogen ◽  
Catalytic Activation

Catalytic Activation of Molecular Hydrogen by Cobalt Cyanide Solutions

1959 ◽  
Vol 63 (3) ◽  
pp. 403-410 ◽  
Author(s):  
G. A. Mills ◽  
S. Weller ◽  
A. Wheeler
Keyword(s):  
Molecular Hydrogen ◽  
Catalytic Activation ◽  
Cyanide Solutions
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