Specific Solvation in Binary Solvent Mixtures. Part I. Variations in Activation Energy of Reactions in Mixed Solvents

1960 ◽  
Vol 82 (19) ◽  
pp. 5129-5135 ◽  
Author(s):  
J. B. Hyne
Keyword(s):  
Activation Energy ◽  
Mixed Solvents ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Specific Solvation ◽  
Binary Solvent Mixtures

scholarly journals Solvation in pure and mixed solvents: Some recent developments

2007 ◽  
Vol 79 (6) ◽  
pp. 1135-1151 ◽  
Author(s):  
Omar A. El Seoud
Keyword(s):  
Hydrogen Bonding ◽  
Hydrophobic Interactions ◽  
Preferential Solvation ◽  
Mixed Solvents ◽  
Effect Of Temperature ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Dispersion Interactions ◽  
Binary Solvent Mixtures ◽  
Recent Developments

The effect of solvents on the spectra, absorption, or emission of substances is called solvatochromism; it is due to solute/solvent nonspecific and specific interactions, including dipole/dipole, dipole-induced/dipole, dispersion interactions, and hydrogen bonding. Thermo-solvatochromism refers to the effect of temperature on solvatochromism. The molecular structure of certain substances, polarity probes, make them particularly sensitive to these interactions; their solutions in different solvents have distinct and vivid colors. The study of both phenomena sheds light on the relative importance of the solvation mechanisms. This account focuses on recent developments in solvation in pure and binary solvent mixtures. The former has been quantitatively analyzed in terms of a multiparameter equation, modified to include the lipophilicity of the solvent. Solvation in binary solvent mixtures is complex because of the phenomenon of "preferential solvation" of the probe by one component of the mixture. A recently introduced solvent exchange model allows calculation of the composition of the probe solvation shell, relative to that of bulk medium. This model is based on the presence of the organic solvent (S), water (W), and a 1:1 hydrogen-bonded species (S-W). Solvation by the latter is more efficient than by its precursor solvents, due to probe/solvent hydrogen-bonding and hydrophobic interactions. Dimethylsulfoxide (DMSO) is an exception, because the strong DMSO/W interactions probably deactivate the latter species toward solvation. The relevance of the results obtained to kinetics of reactions is briefly discussed by addressing temperature-induced desolvation of the species involved (reactants and activated complexes) and the complex dependence of kinetic data (observed rate constants and activation parameters) in binary solvent mixtures on medium composition.

scholarly journals Solubility modelling, solution thermodynamics and preferential solvation of hymecromone in binary solvent mixtures of N,N-dimethylformamide + methanol, ethanol or n-propanol

RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46378-46387 ◽  
Author(s):  
Xinbao Li ◽  
Jiao Chen ◽  
Gaoquan Chen ◽  
Hongkun Zhao
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solution Thermodynamics ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Binary Solvent Mixtures

Solubilities of hymecromone in neat solvents of N,N-dimethylformamide (DMF), methanol, ethanol and n-propanol, and their binary mixed solvents of DMF + methanol, DMF + ethanol and DMF + n-propanol were determined.

The electrospinning behavior of poly(vinyl alcohol) in DMSO–water binary solvent mixtures

RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 102947-102955 ◽  
Author(s):  
Deepika Gupta ◽  
Manjeet Jassal ◽  
Ashwini K. Agrawal
Keyword(s):  
Ternary System ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Binary Solvent Mixtures ◽  
Polymer Interactions ◽  
Solvent Solvent

The fiber diameters obtained from PVA–DMSO–water ternary system are the result of the interplay between the solvent–solvent and solvent–polymer interactions.

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