STERIC EFFECTS ON NITROGEN HYPERFINE COUPLING IN METHYL SUBSTITUTED MONO- AND DINITROBENZENE ANION RADICALS

1961 ◽  
Vol 83 (16) ◽  
pp. 3532-3533 ◽  
Author(s):  
David H. Geske ◽  
John L. Ragle
1971 ◽  
Vol 49 (21) ◽  
pp. 3529-3535 ◽  
Author(s):  
F. C. Adam ◽  
C. R. Kepford

The radical anions of biphenyl and some of its bridged derivatives have been studied by e.s.r. It is found that the proton hyperfine coupling constants change monotonically through the series of radical anions derived from biphenyl, 9,10-dihydrophenanthrene, fluorene, dibenzothiophene, and dibenzofuran. Deuterations have been carried out for the latter two compounds and the hyperfine coupling constants are assigned to specific positions in these anions. The data are displayed in the form of a correlation diagram from which assignments for other bridged biphenyl anions can be made.


1969 ◽  
Vol 73 (12) ◽  
pp. 4389-4391 ◽  
Author(s):  
Wayne C. Danen ◽  
Terry T. Kensler ◽  
J. G. Lawless ◽  
M. F. Marcus ◽  
M. D. Hawley

1984 ◽  
Vol 106 (11) ◽  
pp. 3140-3144 ◽  
Author(s):  
Robert K. Norris ◽  
Steven D. Barker ◽  
P. Neta

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