scholarly journals DERIVATIVES OF TRIHALOGEN TERTIARY-BUTYL ALCOHOLS. III. THE BENZOIC ACID ESTER OF TRICHLORO-TERTIARY-BUTYL ALCOHOL OR CHLORETONE BENZOIC ACID ESTER.

1920 ◽  
Vol 42 (7) ◽  
pp. 1502-1507 ◽  
Author(s):  
T. B. Aldrich
1984 ◽  
Vol 62 (6) ◽  
pp. 1003-1007 ◽  
Author(s):  
R. C. Mehrotra ◽  
Jagvir Singh

Nickel(II) tetraisopropoxyaluminate undergoes alcoholysis reactions with various alcohols and acetylacetone to yield products with the composition: Ni[Al(OR)4]2 (when ROH = methanol, ethanol, 2,2,2-trifluoroethanol, 2,2,2-trichloroethanol, n-butanol, and 1,3-dichloro-2-propanol); Ni[Al(O-i-Pr)(O-t-Bu)3]2 (with tertiary butyl alcohol); Ni[Al(O-i-Pr)2(O-t-Am)2]2 (with tertiary amyl alcohol); and Ni[Al(O-i-Pr)2(acac)2] (with acetylacetone). On the basis of their visible reflectance and infrared spectra along with molecular weights and magnetic susceptibilities, and octahedral geometry is tentatively suggested for these complexes in the solid state with indications of an equilibrium between tetrahedral and octahedral forms in solution. The alkoxy ligands have also been fitted into the spectrochemical and nephelauxetic series.


2006 ◽  
Vol 312 (1-2) ◽  
pp. 131-136 ◽  
Author(s):  
JingXia Cui ◽  
ChunLei Li ◽  
YingJie Deng ◽  
YongLi Wang ◽  
Wei Wang

2010 ◽  
Vol 260 (1) ◽  
pp. 77-83 ◽  
Author(s):  
E.A. Cohen ◽  
B.J. Drouin ◽  
E.A. Valenzuela ◽  
R.C. Woods ◽  
W. Caminati ◽  
...  

1961 ◽  
Vol 39 (7) ◽  
pp. 1424-1433 ◽  
Author(s):  
K. M. Bell ◽  
C. A. McDowell

The mercury-photosensitized oxidation of isobutane has been studied over a wide range of pressures of the hydrocarbon and oxygen, in a conventional static photochemical apparatus at the temperatures of 30 °C and 100 °C. The main products of the reaction are tertiary butyl hydroperoxide, together with tertiary butyl alcohol, acetone, and corresponding small quantities of formaldehyde and methyl alcohol. Isobutyraldehyde was also detected; ditertiary butyl peroxide being notably absent. Peroxide yields suggest that a reaction between an excited isobutane molecule and oxygen is important in the initiation processes and that peroxide is formed in the reaction[Formula: see text]


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