THE COUPLING ACTION OF THE GRIGNARD REAGENT. II METHYLMAGNESIUM IODIDE AND THE BENZYL HALIDES

1926 ◽  
Vol 48 (10) ◽  
pp. 2681-2689 ◽  
Author(s):  
Reynold C. Fuson
Keyword(s):  
Grignard Reagent ◽  
Methylmagnesium Iodide ◽  
Benzyl Halides

Mechanism of Acetal Cleavage with Methylmagnesium Iodide

1985 ◽  
Vol 38 (7) ◽  
pp. 1031
Author(s):  
AD Abell ◽  
RA Massy-Westropp
Keyword(s):  
Grignard Reagent ◽  
Tertiary Alcohol ◽  
Methyl Group ◽  
Methylmagnesium Iodide ◽  
Oxygen Bond

The reaction of methylmagnesium iodide with methyl (1R,3S,5R)-1-(furan- 3′-yl)-5-methyl-2,8-dioxabicyclo[3.2.1]octane-3-carboxylate (2) gives products arising from regioselective carbon-oxygen bond fission and intermolecular transfer of the methyl group of the Grignard reagent to the intermediate oxocarbonium ion, in addition to the usual tertiary alcohol.

Behaviour of 2′-O-p-toluenesulfonyl uridine towards excess of a Grignard reagent

1989 ◽  
Vol 67 (4) ◽  
pp. 708-709 ◽  
Author(s):  
Annie Grouiller ◽  
Hassan Essadiq
Keyword(s):  
Grignard Reagent ◽  
Grignard Reaction ◽  
Methylmagnesium Iodide

Two C-methylated base nucleosides were obtained when 2′-O-tosyl-5′-O-trityluridine was reacted with 30 equivalents of methylmagnesium iodide. Keywords: nucleoside, Grignard reaction, C-methyl pyrimidinone, anhydro derivative, arabinofuranosyl.

scholarly journals Low-valent dialkoxytitanium(ii): a useful tool for the synthesis of functionalized seven-membered ring compounds

2021 ◽  
Vol 57 (29) ◽  
pp. 3603-3606
Author(s):  
Florent Bodinier ◽  
Youssouf Sanogo ◽  
Janick Ardisson ◽  
Marie-Isabelle Lannou ◽  
Geoffroy Sorin
Keyword(s):  
Grignard Reagent ◽  
Membered Ring ◽  
Ring Compounds ◽  
Low Valent

Herein, we describe unprecedented access to all-carbon or heterocyclic seven-membered ring frameworks from 1,8-ene-ynes promoted by inexpensive low-valent titanium(ii) species, readily available from a combination of Ti(OiPr)4 and Grignard reagent.

Facile intramolecular cyclization of an olefinic grignard reagent

1966 ◽  
Vol 7 (36) ◽  
pp. 4297-4301 ◽  
Author(s):  
Herman G. Richey ◽  
Thomas C. Rees
Keyword(s):  
Intramolecular Cyclization ◽  
Grignard Reagent

Phosphine-Catalyzed Cross-Coupling of Benzyl Halides and Fumarates

2021 ◽  
Author(s):  
Tingting Yan ◽  
Kaki Raveendra Babu ◽  
Yong Wu ◽  
Yang Li ◽  
Yuhai Tang ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Benzyl Halides
Sign in / Sign up

Export Citation Format

Share Document