EQUILIBRIUM BETWEEN CRYSTALLINE ZINC HYDROXIDE AND AQUEOUS SOLUTIONS OF AMMONIUM HYDROXIDE AND OF SODIUM HYDROXIDE

1927 ◽  
Vol 49 (6) ◽  
pp. 1419-1431 ◽  
Author(s):  
Harold G. Dietrich ◽  
John Johnston
Keyword(s):  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Ammonium Hydroxide ◽  
Zinc Hydroxide

scholarly journals Investigating the Effects of Surface Adsorbates on Gold and Palladium Deposition on Carbon

2021 ◽  
Author(s):  
Bethany Bowden ◽  
Josh A. Davies-Jones ◽  
Matthew Davies ◽  
Philip R. Davies ◽  
David J. Morgan ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Ammonium Hydroxide ◽  
Ammonium Ion ◽  
Metallic State ◽  
Chloroauric Acid ◽  
Final State ◽  
Ammonium Thiosulfate ◽  
Surface Adsorbates ◽  
Surface Hydroxyls ◽  
High Concentrations

AbstractSurface functional groups have a strong influence on the deposition and final state of nanoparticles adsorbed on to the surface, a role discussed by Professor Spencer in his work. This tribute to Spencer explores the formation of hydroxyls, thiosulfates, sulfites and sulfur atoms on carbon (HOPG) surfaces and their effect on the deposition of gold and palladium from aqueous solutions. Hydroxyls formed from ammonium hydroxide treatment have identical behaviour to those formed by acid treatment, and gold adsorption from Au3+ solutions gives Au0 initially, with Au3+ formed at higher concentrations on these surfaces. In contrast, palladium adsorption is hindered by the presence of the hydroxyls and there is no indication of any reduction to the metallic state. Ammonium thiosulfate adsorbs dissociatively from aqueous solutions on HOPG if the surface is pre-activated by the presence of surface hydroxyls. At low concentrations of ammonium thiosulfate, adsorbed sulfite and sulfur are formed in equimolar concentrations whereas adsorption of high concentrations of ammonium thiosulfate gives some degree of molecular adsorption, with evidence in XP spectra for an ammonium ion and a sulfur 2p peak at 282.9 eV attributed to the undissociated thiosulfate ion. Both sulfur and the sulfite are stable at the surface in neutral solutions but the sulfite desorbs when treated with acidified solutions (~ pH ≤ 6). These two groups are also stable at 373 K but begin to desorb by 473 K. Exposure to a weak chloroauric acid solution causes the desorption of the sulfite and formation of a gold species with an XP binding energy of 84.6 eV; we cannot determine from the present data whether this peak is due to a Au(I) state or very small nanoparticles of Au(0). Graphic Abstract

The alkali-induced elimination of phosphate from β-casein

1972 ◽  
Vol 39 (2) ◽  
pp. 189-194 ◽  
Author(s):  
W. Manson ◽  
T. Carolan
Keyword(s):  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Inorganic Phosphate ◽  
Type A ◽  
Dilute Aqueous Solutions

SummaryThe dephosphorylation of β-casein, type A1, by dilute aqueous solutions of sodium hydroxide has been studied. It has been found that the mechanism whereby inorganic phosphate is liberated by the action of alkali is one of β-elimination from O-phosphoserine residues which are themselves converted initially to dehydroalanyl residues.

Electrolytic Interaction of Nylon with Aqueous Solutions of Sodium Hydroxide

1952 ◽  
Vol 56 (1) ◽  
pp. 50-56 ◽  
Author(s):  
Frederick T. Wall ◽  
Thomas J. Swoboda
Keyword(s):  
Aqueous Solutions ◽  
Sodium Hydroxide

Adhesion of Rubber to Magnesium Alloys in the Presence of Nickel Branched Alkyl Carboxylates

2003 ◽  
Vol 76 (4) ◽  
pp. 1019-1030 ◽  
Author(s):  
K. Mori ◽  
X. Shi ◽  
H. Hirahara ◽  
Y. Oishi
Keyword(s):  
Aqueous Solution ◽  
Zinc Oxide ◽  
Magnesium Alloy ◽  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Magnesium Alloys ◽  
Peel Strength ◽  
Magnesium Alloy Az31 ◽  
Rubber Compounds ◽  
Alkyl Carboxylates

Abstract The authors investigated the adhesion of rubber compounds containing nickel blanched alkyl carboxylate to surface treated magnesium alloys during curing. Ni i-octylate and Ni i-stearate were used as nickel branched alkyl carboxylate. Rubbers used in the study did not adhere at all to magnesium alloys, such as AZ91, AZ31, AZ 21, and M1 washed with acetone; not even in the presence of Ni i-octylate. Among numerous treating solutions, only sodium hydroxide aqueous solution was effective for adhesion of rubber to magnesium alloys. Adhesion of rubber to magnesium alloy AZ31 treated in 0.5M- sodium hydroxide aqueous solution for 10 min at 80 °C yielded high peel strength and a 100% rubber coverage. Peel strength and a 100% rubber coverage varied with the concentration of additives, such as curing accelerators, sulfur, zinc oxide and Ni-type adhesive accelerators. Ni branched alkyl carboxylates such as Ni i-octylate and Ni i-stearate were effective for accelerating the adhesion of rubber to magnesium alloys treated in sodium hydroxide aqueous solutions during curing. The authors postulate that Ni branched alkyl carboxylate acts to yield interface bonds between magnesium alloys and rubber or Ni-S-rubber linkage.

Enhanced Cu (II) Adsorption from Aqueous Solutions by Sawdust (Quercus mongolica) Pretreated by Ionic Liquid-Water Mixture

2013 ◽  
Vol 750-752 ◽  
pp. 1354-1357
Author(s):  
Ning Ning Ma ◽  
Peng Wei ◽  
Li Gang Wei ◽  
Ying Chong Ma ◽  
Kun Lan Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Adsorption Capacity ◽  
Liquid Water ◽  
Water Mixture ◽  
Quercus Mongolica ◽  
Initial Ph ◽  
Conventional Methods

This work investigated the feasibility of Quercus mongolica sawdust pretreated by an ionic liquid-water mixture as a biosorbent for Cu (II) removal from aqueous solutions. Maximum Cu (II) biosorption of 32.6 mg/g is obtained at initial pH 4.3 using sawdust pretreated by a 1-butyl-3-methylimidazolium chloride ([C4miCl)-water mixture (IL content 60%) at 90oC, which is higher than that of unpretreated sawdust (23.0 mg/g, initial pH 6.1). The proposed method is effective in enhancing adsorption capacity of the biomass in comparison to the conventional methods using sulfur acid or sodium hydroxide solutions.

RECOVERY OF LACTOSE FROM AQUEOUS SOLUTIONS: PRECIPITATION WITH CALCIUM HYDROXIDE AND SODIUM HYDROXIDE

1980 ◽  
Vol 45 (2) ◽  
pp. 362-366 ◽  
Author(s):  
DOUGLAS B. MC COMMINS ◽  
RICHARD A. BERN HARD ◽  
T.A. NICKERSON
Keyword(s):  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Calcium Hydroxide
Sign in / Sign up

Export Citation Format

Share Document