X-RAY INVESTIGATIONS OF OPTICALLY ACTIVE COMPOUNDS I. A PROOF OF MOLECULAR ASYMMETRY IN OPTICALLY ACTIVE PHENYLAMINOACETIC ACID1

1929 ◽  
Vol 51 (9) ◽  
pp. 2796-2807 ◽  
Author(s):  
George L. Clark ◽  
G. Robert Yohe
Keyword(s):  
Optically Active ◽  
Active Compounds ◽  
X Ray ◽  
Molecular Asymmetry

Correlation of Electrical, Structural, and Optical Properties of Erbium In Silicon

1993 ◽  
Vol 301 ◽  
Author(s):  
J. L. Benton ◽  
D. J. Eaglesham ◽  
M. Almonte ◽  
P. H. Citrin ◽  
M. A. Marcus ◽  
...  
Keyword(s):  
Root Function ◽  
Free Exciton ◽  
Excitation Power ◽  
Optically Active ◽  
Photoluminescence Intensity ◽  
Square Root ◽  
Structural And Optical Properties ◽  
X Ray ◽  
X Ray Absorption ◽  
Donor Activity

ABSTRACTAn understanding of the electrical, structural, and optical properites of Er in Si is necessary to evaluate this system as an opto-electronic material. Extended x-ray absorption fine structure, EXAFS, measurements of Er-implanted Si show that the optically active impurity complex is Er surrounded by an O cage of 6 atoms. The Er photoluminescence intensity is a square root function of excitation power, while the free exciton intensity increases linearly. The square root dependence of the 1.54μm-intensity is independent of measurement temperature and independent of co-implanted species. Ion-implantation of Er in Si introduces donor activity, but spreading resistance carrier concentration profiles indicate that these donors do not effect the optical activity of the Er.

An Oxidative Decarboxylation of 7-Oxopodocarpic Acid Derivatives

1990 ◽  
Vol 43 (5) ◽  
pp. 883 ◽  
Author(s):  
RC Cambie ◽  
HM Craw ◽  
CEF Rickard ◽  
JD Robertson ◽  
PS Rutledge ◽  
...  
Keyword(s):  
Optically Active ◽  
Oxidative Decarboxylation ◽  
X Ray ◽  
X Ray Crystallography

Treatment of the 7-oxopodocarpic acid derivatives (1) and (3) with 2,3-dichloro-5,6-dicyanobenzoquinone affords the conjugated dienones (5) and (6) directly. The latter compounds have potential as optically active relays for the synthesis of 3-oxygenated diterpenoids . The stereochemistry of an epoxide (7) formed from the dienone (5) has been confirmed by X-ray crystallography.

Optically Active Compounds Related to Methadon

1949 ◽  
Vol 71 (2) ◽  
pp. 460-462 ◽  
Author(s):  
Albert. Pohland ◽  
Frederick J. Marshall ◽  
Thomas P. Carney
Keyword(s):  
Optically Active ◽  
Active Compounds

Synthesis and resolution of an asymmetric arsonium cation. Crystal and molecular structures of (R)-Benzyl(methyl)(4-methylphenyl)(naphthalen-1-yl)- arsonium bromide and hexafluorophosphate

1984 ◽  
Vol 37 (6) ◽  
pp. 1171 ◽  
Author(s):  
DG Allen ◽  
CL Raston ◽  
BW Skelton ◽  
AH White ◽  
SB Wild
Keyword(s):  
Ion Exchange ◽  
Absolute Configuration ◽  
Optically Active ◽  
Molecular Structures ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
X Ray ◽  
Crystal And Molecular Structures ◽  
Ion Exchange Column ◽  
Optically Pure

The (�)-benzyl(methyl)(4-methylphenyl)(naphthalen-1-yl)arsonium cation has been synthesized and subsequently resolved by fractional crystallization of monohydrogen [R-(R*,R*)]-2,3-bis(benzoyloxy)- butanedioate salts. The separated diastereoisomers were converted into the corresponding optically active arsonium bromides by ion-exchange column chromatography. The absolute configuration of the arsonium cation exhibiting a positive rotation at 589 nm (sodium D line) has been established as (R) by single-crystal X-ray analysis of both the bromide and hexafluorophosphate salts. The arsonium bromide with [α]D + 54.8�(c, 0.62 in CH2Cl2) crystallizes in the orthorhombic space group P212121 (D24, No.19) with a 22.472(8), b 15.724(7), c 12.585(5) � and U 4447(3) �3. The corresponding hexafluorophosphate with [α]D + 19.3� (c, 0.5 in CH2Cl2) crystallizes in the same space group with a 23.56(2), b 16.40(1), c 13.12(1) � and U 5067(6) � 3. Benzylidene transfer to benzaldehyde from the arsonium ylide derived from either of the arsonium salts produced optically pure (–)-(S)-methyl(4-methylphenyl)(naphthalen-1-yl)arsine, [α]D - 115.9� (c, 0.593 in CHCl3), and partly resolved [R-(R*,R*)]-2,3-diphenyloxiran.

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