Solubility Relations of the Ternary System Magnesium Nitrate—Nitric Acid—Water at 25°

1933 ◽  
Vol 55 (12) ◽  
pp. 4825-4827 ◽  
Author(s):  
Warren W. Ewing ◽  
Ernst Klinger
1931 ◽  
Vol 0 (0) ◽  
pp. 1753-1757 ◽  
Author(s):  
Henry George Denham ◽  
David Andrew Dick

1963 ◽  
Vol 41 (2) ◽  
pp. 527-530 ◽  
Author(s):  
J. Gaunt ◽  
I. J. Bastien ◽  
M. Adelman

Phase equilibrium studies were carried out on the system UO2(NO3)2−HNO3−H2O between the temperatures of −10 °C and +49.1 °C over a wide concentration range of both UO2(NO3)2 and HNO3. No phase separation occurred above 49.1 °C for the concentrations studied. The three hydrates of UO2(NO3)2 were identified in the solid phase, and a new complex of UO2(NO3)2, possibly UO2(NO3)2.3HNO3, was separated as the solid phase at higher nitric acid concentrations.


1940 ◽  
Vol 62 (8) ◽  
pp. 2174-2176 ◽  
Author(s):  
Warren W. Ewing ◽  
Charles F. Glick

1933 ◽  
Vol 55 (12) ◽  
pp. 4830-4832 ◽  
Author(s):  
Warren W. Ewing ◽  
Atwood J. Ricards ◽  
William J. Taylor ◽  
David W. Winkler

2010 ◽  
Vol 75 (1) ◽  
pp. 113-128 ◽  
Author(s):  
Simona Murko ◽  
Radmila Milacic ◽  
Marjan Veber ◽  
Janez Scancar

The applicability of nitric acid, palladium nitrate and a mixture of palladium and magnesium nitrate as matrix modifiers was estimated for the accurate and reproducible determination of cadmium (Cd), lead (Pb) and arsenic (As) in sediments of the Sava River by electrothermal atomic absorption spectrometry, ETAAS. Decomposition of the samples was done in a closed vessel microwave-assisted digestion system using nitric, hydrochloric and hydrofluoric acids, followed by the addition of boric acid to convert the fluorides into soluble complexes. The parameters for the determination of Cd, Pb and As in sediments were optimized for each individual element and for each matrix modifier. In addition, two sediment reference materials were also analyzed. In determination of Cd and Pb, nitric acid was found to be the most appropriate matrix modifier. The accurate and reliable determination of Cd and Pb in sediments was possible also in the presence of boric acid. The use of a mixture of palladium and magnesium nitrate efficiently compensated for matrix effects and enabled the accurate and reliable determination of As in the sediments. Quantification of Cd and As was performed by calibration using acid matched standard solutions, while the standard addition method was applied for the quantification of Pb. The repeatability of the analytical procedure for the determination of Cd, Pb and As in sediments was ?5 % for Cd, ?4 % for Pb and ?2 % for As. The LOD values of the analytical procedure were found to be 0.05 mg/kg for Cd and 0.25 mg/kg for Pb and As, while the LOQ values were 0.16 mg/kg for Cd and 0.83 mg/kg for Pb and As. Finally, Cd, Pb and As were successfully determined in sediments of the Sava River in Slovenia.


1956 ◽  
Vol 48 (4) ◽  
pp. 816-816
Author(s):  
C. H. Duffy ◽  
W. H. Corcoran ◽  
B. H. Sage

2008 ◽  
Vol 163 (2) ◽  
pp. 285-293 ◽  
Author(s):  
Michael Epstein ◽  
Hans K. Fauske ◽  
Charles F. Askonas ◽  
Marc A. Vial ◽  
Patricia Paviet-Hartmann

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