The Compressibility of Solutions. I. The Apparent Molal Compressibility of Strong Electrolytes

1933 ◽  
Vol 55 (7) ◽  
pp. 2709-2718 ◽  
Author(s):  
Frank T. Gucker
Keyword(s):  
Strong Electrolytes ◽  
Apparent Molal Compressibility

The anomalous valency effect of strong electrolytes in aqueous solutions

1934 ◽  
Vol 6 ◽  
pp. 116-125 ◽  
Author(s):  
J. B. Chloupek ◽  
Vl. Z. Daneš ◽  
B. A. Danešová
Keyword(s):  
Aqueous Solutions ◽  
Strong Electrolytes

THE ACCUMULATION OF STRONG ELECTROLYTES IN LIVING CELLS

Science ◽  
1931 ◽  
Vol 73 (1900) ◽  
pp. 589-590 ◽  
Author(s):  
S. C. Brooks
Keyword(s):  
Living Cells ◽  
Strong Electrolytes

NMR Studies of Aqueous Electrolyte Solutions. IV. Hydration Numbers of Strong Electrolytes Determined from Temperature Effects on Proton Shifts

1971 ◽  
Vol 54 (1) ◽  
pp. 178-181 ◽  
Author(s):  
Brother Ferdinand J. Vogrin ◽  
Paul S. Knapp ◽  
William L. Flint ◽  
Arthur Anton ◽  
Gerald Highberger ◽  
...  
Keyword(s):  
Temperature Effects ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Hydration Numbers ◽  
Nmr Studies ◽  
Aqueous Electrolyte Solutions ◽  
Strong Electrolytes

scholarly journals The viscosity of strong electrolytes measured by a differential method

1934 ◽  
Vol 145 (855) ◽  
pp. 475-488 ◽  
Keyword(s):  
Dielectric Constant ◽  
Empirical Equation ◽  
Relative Viscosity ◽  
Absolute Temperature ◽  
Differential Method ◽  
Theoretical Equation ◽  
Electronic Charge ◽  
Accurate Data ◽  
Avogadro’S Number ◽  
Strong Electrolytes

Until quite recently no satisfactory equation had been obtained for the representation of the viscosity of dilute solutions of strong electrolytes. An empirical equation was recently proposed by Jones and Dole to fit the only accurate data then available. Their equation may be represented thus : η = 1 + A √ c + B c , η = relative viscosity of the solution c = concentration in moles per litre A and B are constants. Jones and Dole realized that the coefficient A is due to interionic forces and in a series of later publications Falkenhagen, Dole and Vernon have deduced a theoretical equation giving values of A in terms of well-known physical constants. Their complete equation may be written η = 1 + ε √N v 1 z 1 /30η 0 √1000D k T ( z 1 + z 2 ) 4 π × [¼ μ 1 z 2 + μ 2 z 1 / μ 1 μ 2 - z 1 z 2 (μ 1 - μ 2 ) 2 /μ 1 μ 2 (√μ 1 z 1 + μ 2 z 2 + √(μ 1 + μ 2 ) ( z 1 + z 2 ) ) 2 ]√ c , where N = Avogadro's number v 1 , v 2 = numbers of ions z 1 , z 2 = valencies of ions μ 1 , μ 2 = absolute mobilities of ions D = dielectric constant of solvent k = Boltzmann's constant ε = electronic charge η 0 = viscosity of solvent T = absolute temperature.

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