The Thermal Decomposition of Gaseous Hydrogen Peroxide

1937 ◽  
Vol 59 (12) ◽  
pp. 2737-2737 ◽  
Author(s):  
L. W. Elder
1937 ◽  
Vol 59 (2) ◽  
pp. 422-422 ◽  
Author(s):  
G. B. Kistiakowsky ◽  
S. L. Rosenberg

2016 ◽  
Vol 57 (4) ◽  
pp. 45-51 ◽  
Author(s):  
Zbigniew Dąbrowiecki ◽  
Małgorzata Dąbrowiecka ◽  
Romuald Olszański ◽  
Piotr Siermontowski

AbstractWhen working in chemical or biological environments, contamination is an extremely dangerous issue for the rescue services of the fire department, police and the army.Modern protective overalls worn by fire fighters or dry “Viking” diving suits made from neoprene or nylon covered with polyurethane, have been proven to ensure sufficient protection. However, once the contaminated area is left, there is a need to perform decontamination of the external and internal surfaces of the protective overalls; in order to ensure the clothing continues to offer a high level of comfort and to retain the durability of said protective clothing, it is of course also necessary to perform a drying procedure.Moreover, there is a risk of a transfer of pathogenic micro-organisms between persons utilising the same protective clothes, particularly in the case of expensive specialist suits. Micro-organisms which may potentially spread through clothing include intestinal bacteria, such as: Salmonella, Shigella, Campylobacter, E. coli (including E. coli O157), C. difficile, viruses inducing infections of the upper respiratory tract and alimentary tract (noraviruses, rotaviruses, adeno and astroviruses). The risk of infection also involves the presence of the flu viruses, herpesviruses and pathogens transferred through skin, such as S. aureus (including MRSA), yeast-like fungi (Candida albicans), fungal strains inducing Tinea pedis and Tinea corporis [1]. Pathogenic micro-organisms can easily transfer from fabric surface onto the body of a person wearing protective clothing.From the numerous available techniques of decontamination of surfaces, equipment and protective clothing we propose to use for this purpose gaseous hydrogen peroxide (H2O2), a very effective biocidal agent. In field conditions, typical for the activities of rescue crews of the fire department, police and army we assume utilisation of a portable decontamination chamber enabling performance of a complete decontamination process.The process lasting approximately 3 hours encompasses 3 phases:• Drying phase;• Decontamination with gaseous hydrogen peroxide;• Catalytic combustion phase of hydrogen peroxide residues to a level safe for the environment.The integrated humidity and H2O2level sensors ensure automatic control of the entire process and the unique distribution system of gaseous H2O2secures full accessibility of the biocidal agent to the external surface of protective clothing as well as its interior. Moreover, the container allows for the conduction of the complete decontamination of the rescue equipment, night vision devices, binoculars, field telephones, radio stations, etc. Upon decontamination cycle completion, we obtain a completely dried suit which can be safely used by another crew member.


1968 ◽  
Author(s):  
K. R. Bilwakesh ◽  
W. A. Strauss ◽  
R. Edse ◽  
E. S. Fishburne

1947 ◽  
Vol 25b (2) ◽  
pp. 135-150 ◽  
Author(s):  
Paul A. Giguère

The decomposition of hydrogen peroxide vapour has been investigated at low pressures (5 to 6 mm.) in the temperature range 50° to 420 °C., for the purpose of determining the effect of the nature and treatment of the active surfaces. The reaction was followed in an all-glass apparatus and, except in one case, with one-litre round flasks as reaction vessels. Soft glass, Pyrex, quartz, and metallized surfaces variously treated were used. In most cases the decomposition was found to be mainly of the first order but the rates varied markedly from one vessel to another, even with vessels made of the same type of glass. On a quartz surface the decomposition was preceded by an induction period at low temperatures. Fusing the glass vessels slowed the reaction considerably and increased its apparent activation energy; this effect was destroyed by acid washing. Attempts to poison the surface with hydrocyanic acid gave no noticeable result. The marked importance of surface effects at all temperatures is considered as an indication that the reaction was predominantly heterogeneous under the prevailing conditions. Values ranging from 8 to 20 kcal. were found for the apparent energy of activation. It is concluded that the decomposition of hydrogen peroxide vapour is not very specific as far as the nature of the catalyst is concerned.


Nature ◽  
1949 ◽  
Vol 163 (4153) ◽  
pp. 876-877 ◽  
Author(s):  
A. B. HART

Author(s):  
Jeremy Corpening ◽  
Stephen Heister ◽  
Willam Anderson ◽  
Benjamin Austin

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