The Osmotic and Activity Coefficient Data of Some Aqueous Salt Solutions from Vapor Pressure Measurements

1937 ◽  
Vol 59 (1) ◽  
pp. 84-90 ◽  
Author(s):  
Robert A. Robinson
Keyword(s):  
Vapor Pressure ◽  
Activity Coefficient ◽  
Pressure Measurements ◽  
Salt Solutions ◽  
Aqueous Salt Solutions ◽  
Vapor Pressure Measurements

scholarly journals Thermochemistry of Polonium Evaporation from LBE

Thermo ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 251-261
Author(s):  
Alexander Aerts
Keyword(s):  
Vapor Pressure ◽  
Activity Coefficient ◽  
Ab Initio ◽  
Chemical Species ◽  
Pressure Measurements ◽  
Chemical Equilibria ◽  
Limit Activity Coefficient ◽  
Nuclear Systems ◽  
Dilute Limit ◽  
Vapor Pressure Measurements

Polonium is formed in relatively large quantities in lead-bismuth eutectic (LBE) cooled nuclear systems. Because of its radiotoxicity and volatility, a good understanding of the chemical equilibria governing polonium release from LBE is required. In this work, a set of thermochemical data is derived for the chemical species involved in the equilibrium between a solution of polonium in LBE and its vapor in inert conditions. The data were obtained by matching thermochemical models with experimental vapor pressure measurements and ab initio results. The dilute-limit activity coefficient of dissolved polonium in LBE is estimated, as well as the solubility of solid lead polonide in LBE. The results indicate that polonium evaporates from LBE according to the experimentally determined Henry’s law, up to dissolved polonium concentrations well above that expected in LBE cooled nuclear systems.

Rapid Vapor-Collection Method for Vapor Pressure Measurements of Low-Volatility Compounds

2020 ◽  
Vol 92 (24) ◽  
pp. 16253-16259
Author(s):  
Megan E. Harries ◽  
Cheryle N. Beuning ◽  
Bridger L. Johnston ◽  
Tara M. Lovestead ◽  
Jason A. Widegren
Keyword(s):  
Vapor Pressure ◽  
Pressure Measurements ◽  
Collection Method ◽  
Vapor Collection ◽  
Vapor Pressure Measurements

scholarly journals Application of a Micro-Flow Regulating Valve in Saturated Vapor Pressure Measurements

Daxue Huaxue ◽  
2021 ◽  
Vol 0 (0) ◽  
pp. 2107062-0
Author(s):  
Shuai Zhang ◽  
Jian Zhang ◽  
Shaowei Bian ◽  
Yaping Zhao ◽  
Li Shen ◽  
...  
Keyword(s):  
Vapor Pressure ◽  
Saturated Vapor Pressure ◽  
Saturated Vapor ◽  
Pressure Measurements ◽  
Micro Flow ◽  
Vapor Pressure Measurements
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