Formation of a 1-Bicyclo[1.1.1]pentyl Anion and an Experimental Determination of the Acidity and C−H Bond Dissociation Energy of 3-tert-Butylbicyclo[1.1.1]pentane

2002 ◽  
Vol 124 (11) ◽  
pp. 2790-2795 ◽  
Author(s):  
Dana R. Reed ◽  
Steven R. Kass ◽  
Kathleen R. Mondanaro ◽  
William P. Dailey
Keyword(s):  
Experimental Determination ◽  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Bond Dissociation

Determination of the heat of formation of trimethylindium and calculation of the mean In—CH3 bond dissociation energy

1968 ◽  
Vol 46 (10) ◽  
pp. 1633-1634 ◽  
Author(s):  
W. D. Clark ◽  
S. J. W. Price
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Chloroform Solution ◽  
Kinetic Studies ◽  
Heat Of Formation ◽  
Enthalpy Of Reaction ◽  
Kcal Mole ◽  
Bond Dissociation ◽  
The Mean

The enthalpy of reaction of In(CH3)3,c with a chloroform solution of bromine is −162.5 kcal mole−1. With this value ΔHf0298[In(CH3)3,c] = 29.5 kcal mole−1 and ΔHf0298[In(CH3)3,g] = 41.1 kcal mole−1. Combining the latter with ΔHf0298[CH3,g] = 33.2 kcal mole−1 and ΔHf0298[In,g] = 58.2 kcal mole−1 then gives E(In—CH3) = 38.9 kcal mole−1. From previous kinetic studies D[(CH3)2In—CH3] + D[In—CH3] = 87.9 kcal mole−1. Hence D[CH3In—CH3] = 28.8 kcal mole−1.

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