Liquid and Vapor Curves in the System Ethyl Alcohol—Benzene—Carbon Tetrachloride at Constant Pressure

1948 ◽  
Vol 70 (5) ◽  
pp. 1723-1727 ◽  
Author(s):  
A. N. Campbell ◽  
W. J. Dulmage
1947 ◽  
Vol 25b (3) ◽  
pp. 228-242 ◽  
Author(s):  
A. N. Campbell ◽  
S. I. Miller

The densities and refractive indices (Nc) of binary and ternary mixtures of benzene, ethyl alcohol, and carbon tetrachloride have been determined at 25 °C. From these data, a method for the analysis of ternary liquid mixtures of these components has been developed. The limit of accuracy in the analysis of ternary mixtures of the pure components is 0.3%. The method can be applied to the analysis of commercial materials with an accuracy of 2.0%.


1908 ◽  
Vol 28 ◽  
pp. 703-704
Author(s):  
G. E. Gibson

WHEN a mixture of ethyl alcohol, benzene, and water is fractionated, a ternary mixture of all three distils over first at a temperature of 68°C.Taylor has made use of this fact in the preparation of the ethyl esters of high boiling-point acids.His method is a great improvement on the old methods, but it is not continuous, and is tedious when large quantities of ester have to be prepared.To remedy these defects the apparatus described in this paper was devised.


A brief review of the condensation theory of Becker & Döring (1935) and Frenkel (1946) is given. It is shown that the theory is subject to the limitation that it assumes that small molecular complexes behave like liquid droplets. This is not the case for complexes consisting of a few molecules only, so that the rate of condensation expected from the theory may be altered by an appreciable amount. The Becker & Döring expression for critical supersaturation is compared with the cloud-chamber measurements of Volmer & Flood (1934), taking into account the rapid heating of the gas after the fast expansion. It is found to be in approximate agreement for water and some of the alcohols, but methyl alcohol, benzene and carbon tetrachloride show large discrepancies. More measurements of critical supersaturations are needed.


1942 ◽  
Vol 46 (8) ◽  
pp. 946-948 ◽  
Author(s):  
H. J. McDonald ◽  
A. F. Kleunder ◽  
R. W. Lane

2017 ◽  
Vol 40 (3) ◽  
pp. 356-364 ◽  
Author(s):  
Ping Tang ◽  
Wenchao Jiang ◽  
Shuguang Lu ◽  
Xiang Zhang ◽  
Yunfei Xue ◽  
...  

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