Organocations in Zeolite Synthesis:  Fused Bicyclo [l.m.0] Cations and the Discovery of Zeolite SSZ-48

2002 ◽  
Vol 124 (24) ◽  
pp. 7024-7034 ◽  
Author(s):  
Greg S. Lee ◽  
Yumi Nakagawa ◽  
Son-Jong Hwang ◽  
Mark E. Davis ◽  
Paul Wagner ◽  
...  
Keyword(s):  
Zeolite Synthesis

ChemInform Abstract: Strategies for Zeolite Synthesis by Design

ChemInform ◽  
2010 ◽  
Vol 27 (18) ◽  
pp. no-no
Author(s):  
M. E. DAVIS
Keyword(s):  
Zeolite Synthesis

scholarly journals Organic-free synthesis of layer-like FAU-type zeolites

2015 ◽  
Vol 51 (2) ◽  
pp. 279-281 ◽  
Author(s):  
A. Inayat ◽  
C. Schneider ◽  
W. Schwieger
Keyword(s):  
Inorganic Salts ◽  
Zeolite Synthesis ◽  
Organic Additives

The presence of simple inorganic salts during zeolite synthesis turned out to be an effective and easy to handle alternative to organic additives to induce the growth of layer-like zeolite morphologies.

scholarly journals Recycling of Waste Solution after Hydrothermal Conversion of Fly Ash on a Semi-Technical Scale for Zeolite Synthesis

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1413
Author(s):  
Rafał Panek ◽  
Jarosław Madej ◽  
Lidia Bandura ◽  
Grzegorz Słowik
Keyword(s):  
Fly Ash ◽  
Nitrogen Adsorption ◽  
Particle Size Analysis ◽  
Al2o3 Content ◽  
Size Analysis ◽  
Zeolite Synthesis ◽  
Hydrothermal Conversion ◽  
Waste Solution ◽  
X Ray ◽  
X Zeolites

Nowadays, using fly ash for zeolites production has become a well-known strategy aimed on sustainable development. During zeolite synthesis in a hydrothermal conversion large amount of post-reaction solution is generated. In this work, the solution was used as a substrate for Na-A and Na-X zeolites synthesis at laboratory and technical scale. Obtained materials were characterized using particle size analysis, X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), transmission electron microscopy (TEM), Fourier transformed infrared spectroscopy (FTIR), and nitrogen adsorption/desorption isotherm. Produced zeolites revealed high purity (>98%) and monomineral zeolitic phase composition. The SiO2 content was in the range 39–42% and 40–38%, whereas Al2O3 content was 23–22% and 25–26% for Na-X and Na-A, respectively. TEM and BET analyses revealed Na-X zeolite pores were almost identical to commercial 13X with SBET in the range 671–734 m2/g. FTIR indicated slight differences between materials obtained at laboratory and technical scale in Si-O-(Si/Al) bridges of the zeolitic skeleton. The results showed good replicability of the laboratory process in the larger scale. The proposed method allows for waste solution reusability with a view to highly pure zeolites production in line with circular economy assumptions.

scholarly journals The increased use value of bamboo leaves as silica source for t-type zeolite synthesis

2018 ◽  
Vol 197 ◽  
pp. 05003 ◽  
Author(s):  
Soni Setiadji ◽  
Citra Deliana Dewi Sundari ◽  
Endang Lala ◽  
Denia Febby Nurbaeti ◽  
Ira Novianti ◽  
...  
Keyword(s):  
Sem Analysis ◽  
High Price ◽  
Heating Process ◽  
Zeolite Synthesis ◽  
X Ray Diffraction ◽  
Cost Performance ◽  
Silica Source ◽  
Bamboo Leaves ◽  
Type Zeolite ◽  
The Cost

T-type zeolite can be used as catalyst, adsorbent, and membranes for gas separation. The synthesis of T-type zeolite needs to be optimized in both of the method and source of precursor, because of its relatively high price. In this research, the synthesis is done using silica extracted from bamboo leaves instead of commercial silica. This increases the value of the bamboo leaves and the cost-performance of zeolite synthesis. The silica was extracted from bamboo leaves ash using alkaline solvent. The extracted silica has 81.76% of purity and an amorphous phase. The T-type zeolite was synthesized using the molar composition of 0.15 Na2O : 0.025 Al : 0.15 K2O : 1 SiO2 : 15 H2O : 0.06 TMAOH, under hydrothermal method and heating process for 4 days, 60°C for 2 days and 120°C for the next 2 days. The characterization method using X-Ray Diffraction and Infra-Red Spectroscopy were performed to confirm the formation of T-type zeolite. The results of Scanning Electron Microscope (SEM) analysis show that the formed T-type zeolite has erionite cylindrical crystal shape.

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